Preparation and Structure of Meta-Hydroxy-Substituted Aryliodonium Salts: New Structural Type of Phenol-Derived Hypervalent Iodine Compounds; European Journal of Organic Chemistry; Vol. 29, iss. 5

Preparation and Structure of Meta-Hydroxy-Substituted Aryliodonium Salts: New Structural Type of Phenol-Derived Hypervalent Iodine Compounds; European Journal of Organic Chemistry; Vol. 29, iss. 5

Bibliographic Details
Parent link:European Journal of Organic Chemistry.— .— Weinheim: Wiley-VCH
Vol. 29, iss. 5.— 2026.— Article number e202501154, 5 p.
Corporate Author: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Other Authors: Yoshimura A. Akira, Larson S. M. Skott, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Lyulyaev A. V. Aleksandr Vitaljevich, Rode G. T. Gregori, Suzuki T. Tatsuya, Ueki A. Akiharu, Saito A. Akio, Zhdankin V. V. Viktor Vladimirovich
Summary:Title screen
The previously unknown meta-hydroxy-substituted aryliodonium salts were prepared by a two-step one-pot synthesis based on the reaction of 3-acetoxy-1-[(diacetoxy)iodo]arenes with arylboronic acids, involving the initial formation of 3-acetoxyphenyl(phenyl)iodonium salts and followed by deacetylation of the intermediate product in the presence of trifluoromethanesulfonic acid. The procedure works well with halogen-, methyl-, methoxycarbonyl-, or methoxy-substituted arylboronic acids as well as naphthalenylboronic acids, phenanthren-9-ylboronic acid, and thiophen-3-ylboronic acid. The structure of 3-hydroxyphenyl(phenyl)iodonium triflate was confirmed by single-crystal X-ray crystallography
Текстовый файл
AM_Agreement
Language:English
Published: 2026
Subjects:
hypervalent iodine
iodine
iodonium
phenols
X-ray
электронный ресурс
труды учёных ТПУ
Online Access:https://doi.org/10.1002/ejoc.202501154
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=687720

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