Preparation and Structure of Meta-Hydroxy-Substituted Aryliodonium Salts: New Structural Type of Phenol-Derived Hypervalent Iodine Compounds; European Journal of Organic Chemistry; Vol. 29, iss. 5
| Parent link: | European Journal of Organic Chemistry.— .— Weinheim: Wiley-VCH Vol. 29, iss. 5.— 2026.— Article number e202501154, 5 p. |
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| Other Authors: | , , , , , , , , |
| Summary: | Title screen The previously unknown meta-hydroxy-substituted aryliodonium salts were prepared by a two-step one-pot synthesis based on the reaction of 3-acetoxy-1-[(diacetoxy)iodo]arenes with arylboronic acids, involving the initial formation of 3-acetoxyphenyl(phenyl)iodonium salts and followed by deacetylation of the intermediate product in the presence of trifluoromethanesulfonic acid. The procedure works well with halogen-, methyl-, methoxycarbonyl-, or methoxy-substituted arylboronic acids as well as naphthalenylboronic acids, phenanthren-9-ylboronic acid, and thiophen-3-ylboronic acid. The structure of 3-hydroxyphenyl(phenyl)iodonium triflate was confirmed by single-crystal X-ray crystallography Текстовый файл AM_Agreement |
| Language: | English |
| Published: |
2026
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| Subjects: | |
| Online Access: | https://doi.org/10.1002/ejoc.202501154 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=687720 |