Preparation and Structure of Meta-Hydroxy-Substituted Aryliodonium Salts: New Structural Type of Phenol-Derived Hypervalent Iodine Compounds; European Journal of Organic Chemistry; Vol. 29, iss. 5
| Parent link: | European Journal of Organic Chemistry.— .— Weinheim: Wiley-VCH Vol. 29, iss. 5.— 2026.— Article number e202501154, 5 p. |
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| Autor corporatiu: | |
| Altres autors: | , , , , , , , , |
| Sumari: | Title screen The previously unknown meta-hydroxy-substituted aryliodonium salts were prepared by a two-step one-pot synthesis based on the reaction of 3-acetoxy-1-[(diacetoxy)iodo]arenes with arylboronic acids, involving the initial formation of 3-acetoxyphenyl(phenyl)iodonium salts and followed by deacetylation of the intermediate product in the presence of trifluoromethanesulfonic acid. The procedure works well with halogen-, methyl-, methoxycarbonyl-, or methoxy-substituted arylboronic acids as well as naphthalenylboronic acids, phenanthren-9-ylboronic acid, and thiophen-3-ylboronic acid. The structure of 3-hydroxyphenyl(phenyl)iodonium triflate was confirmed by single-crystal X-ray crystallography Текстовый файл AM_Agreement |
| Idioma: | anglès |
| Publicat: |
2026
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| Matèries: | |
| Accés en línia: | https://doi.org/10.1002/ejoc.202501154 |
| Format: | Electrònic Capítol de llibre |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=687720 |
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| 200 | 1 | |a Preparation and Structure of Meta-Hydroxy-Substituted Aryliodonium Salts: New Structural Type of Phenol-Derived Hypervalent Iodine Compounds |f A. Yoshimura, S. M. Larson, M. S. Yusubov [et al.] | |
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| 300 | |a Title screen | ||
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| 330 | |a The previously unknown meta-hydroxy-substituted aryliodonium salts were prepared by a two-step one-pot synthesis based on the reaction of 3-acetoxy-1-[(diacetoxy)iodo]arenes with arylboronic acids, involving the initial formation of 3-acetoxyphenyl(phenyl)iodonium salts and followed by deacetylation of the intermediate product in the presence of trifluoromethanesulfonic acid. The procedure works well with halogen-, methyl-, methoxycarbonyl-, or methoxy-substituted arylboronic acids as well as naphthalenylboronic acids, phenanthren-9-ylboronic acid, and thiophen-3-ylboronic acid. The structure of 3-hydroxyphenyl(phenyl)iodonium triflate was confirmed by single-crystal X-ray crystallography | ||
| 336 | |a Текстовый файл | ||
| 371 | 0 | |a AM_Agreement | |
| 461 | 1 | |t European Journal of Organic Chemistry |c Weinheim |n Wiley-VCH | |
| 463 | 1 | |t Vol. 29, iss. 5 |v Article number e202501154, 5 p. |d 2026 | |
| 610 | 1 | |a hypervalent iodine | |
| 610 | 1 | |a iodine | |
| 610 | 1 | |a iodonium | |
| 610 | 1 | |a phenols | |
| 610 | 1 | |a X-ray | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 701 | 1 | |a Yoshimura |b A. |c chemical engineer |c Professor of Tomsk Polytechnic University |f 1981- |g Akira |9 21126 | |
| 701 | 1 | |a Larson |b S. M. |g Skott | |
| 701 | 1 | |a Yusubov |b M. S. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1961- |g Mekhman Suleiman-Ogly (Suleimanovich) |9 15928 | |
| 701 | 1 | |a Lyulyaev |b A. V. |c biotechnologist |c Engineer of Tomsk Polytechnic University |f 2000- |g Aleksandr Vitaljevich |9 89339 | |
| 701 | 1 | |a Rode |b G. T. |g Gregori | |
| 701 | 1 | |a Suzuki |b T. |g Tatsuya | |
| 701 | 1 | |a Ueki |b A. |g Akiharu | |
| 701 | 1 | |a Saito |b A. |g Akio | |
| 701 | 1 | |a Zhdankin |b V. V. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1956- |g Viktor Vladimirovich |9 18915 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий |c (2017- ) |9 28334 |
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