Effect of heat treatment on the corrosion inhibition performance of ZnO nanoparticles for high-carbon steel; Journal of the Indian Chemical Society; Vol. 103, iss. 8

Effect of heat treatment on the corrosion inhibition performance of ZnO nanoparticles for high-carbon steel; Journal of the Indian Chemical Society; Vol. 103, iss. 8

書誌詳細
Parent link:Journal of the Indian Chemical Society.— .— Amsterdam: Elsevier Science Publishing Company Inc.
Vol. 103, iss. 8.— 2026.— Article number 102825, 20 p.
第一著者: Chzhun Linzhu
その他の著者: Dubinina O. V. Oksana Valerievna
要約:Title screen
This study investigates the relationship between the microstructural condition of high-carbon T8 steel and the corrosion inhibition performance of zinc oxide nanoparticles. Steel specimens were heat-treated at 550 °C and 700 °C (15 min, water quenching, tempering at 200 °C for 2 h). ZnO nanoparticles were synthesized via microwave-assisted synthesis (MAS, 87.2 ± 2.7 nm) and nano-spray drying synthesis (NSDS, 49.6 ± 1.3 nm). Heat treatment at 700 °C induces substantial softening (168.1-181.8 HV) and extreme carbon redistribution (0.20-5.44 wt%). Although it increases the corrosion rate from 0.34 ± 0.03 to 0.75 ± 0.11 mg s−1 cm−2, it enhances the inhibition efficiency of ZnO to 88.9% in 0.1 M NaCl and 50.7% in acidic media. Electrochemical analysis reveals that ZnO acts primarily as a cathodic inhibitor in neutral chloride environments via physical barrier formation, while exhibiting limited stability in acids due to proton-assisted dissolution. The finest NSDS-ZnO particles achieve inhibition efficiencies rising from 15.7% on untreated steel to 50.7% on 700 °C-treated specimens. These findings establish that microstructural features conventionally associated with reduced corrosion resistance serve as preferential anchoring sites for nanoparticle adsorption, enabling the formation of robust protective films
Текстовый файл
AM_Agreement
言語:英語
出版事項: 2026
主題:
электронный ресурс
труды учёных ТПУ
High-carbon steel
Heat treatment
Microstructure
Zinc oxide nanoparticles
Corrosion inhibition
Electrochemical analysis
オンライン･アクセス:https://doi.org/10.1016/j.jics.2026.102825
フォーマット: 電子媒体 図書の章
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=687137

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