Metal-Organic Framework [Cd2(Bdc)2Dabco]: Synthesis, Crystal Structure, and Photoluminescence Properties; Russian Journal of Coordination Chemistry; Vol. 51, iss. 8
| Parent link: | Russian Journal of Coordination Chemistry=Координационная химия.— .— Berlin: Springer Nature Vol. 51, iss. 8.— 2025.— P. 703-709 |
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| Altri autori: | Zaguzin A. S. Aleksandr Sergeevich, Zaytsev A. I. Aleksandr Ivanovich, Korobeynikov N. A. Nikita Alekseevich, Rakhmanova M. I. Mariana Ivanovna, Bondarenko M. A. Mikhail Aleksandrovich, Shurikov M. K. Matvey Konstantinovich, Fedin V. P. Vladimir Petrovich, Adonin S. A. Sergey Aleksandrovich |
| Riassunto: | Title screen The reaction of cadmium nitrate, terephthalic acid (Bdc), and 1,4-diazabicyclo[2.2.2]octane (Dabco) in N,N-dimethylformamide affords the new coordination polymer [Cd2(Bdc)2Dabco] (I), whose structure is determined by X-ray diffraction (CIF file CCDC no. 2441975). This coordination polymer (or metal-organic framework) demonstrates high thermal stability: the fast mass loss starts at temperatures above 420°C. Compound I exhibits photoluminescence at 430 nm (λex = 380 nm) with lifetimes of 5 and 12 ns and a quantum yield of 6% Текстовый файл AM_Agreement |
| Lingua: | inglese |
| Pubblicazione: |
2025
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| Soggetti: | |
| Accesso online: | https://doi.org/10.1134/S1070328425600901 |
| Natura: | Elettronico Capitolo di libro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=685412 |
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