Metal-Organic Framework [Cd2(Bdc)2Dabco]: Synthesis, Crystal Structure, and Photoluminescence Properties

Dettagli Bibliografici
Parent link:Russian Journal of Coordination Chemistry=Координационная химия.— .— Berlin: Springer Nature
Vol. 51, iss. 8.— 2025.— P. 703-709
Altri autori: Zaguzin A. S. Aleksandr Sergeevich, Zaytsev A. I. Aleksandr Ivanovich, Korobeynikov N. A. Nikita Alekseevich, Rakhmanova M. I. Mariana Ivanovna, Bondarenko M. A. Mikhail Aleksandrovich, Shurikov M. K. Matvey Konstantinovich, Fedin V. P. Vladimir Petrovich, Adonin S. A. Sergey Aleksandrovich
Riassunto:Title screen
The reaction of cadmium nitrate, terephthalic acid (Bdc), and 1,4-diazabicyclo[2.2.2]octane (Dabco) in N,N-dimethylformamide affords the new coordination polymer [Cd2(Bdc)2Dabco] (I), whose structure is determined by X-ray diffraction (CIF file CCDC no. 2441975). This coordination polymer (or metal-organic framework) demonstrates high thermal stability: the fast mass loss starts at temperatures above 420°C. Compound I exhibits photoluminescence at 430 nm (λex = 380 nm) with lifetimes of 5 and 12 ns and a quantum yield of 6%
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Lingua:inglese
Pubblicazione: 2025
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Accesso online:https://doi.org/10.1134/S1070328425600901
Natura: Elettronico Capitolo di libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=685412

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