Metal-Organic Framework [Cd2(Bdc)2Dabco]: Synthesis, Crystal Structure, and Photoluminescence Properties
| Parent link: | Russian Journal of Coordination Chemistry=Координационная химия.— .— Berlin: Springer Nature Vol. 51, iss. 8.— 2025.— P. 703-709 |
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| Other Authors: | , , , , , , , |
| Summary: | Title screen The reaction of cadmium nitrate, terephthalic acid (Bdc), and 1,4-diazabicyclo[2.2.2]octane (Dabco) in N,N-dimethylformamide affords the new coordination polymer [Cd2(Bdc)2Dabco] (I), whose structure is determined by X-ray diffraction (CIF file CCDC no. 2441975). This coordination polymer (or metal-organic framework) demonstrates high thermal stability: the fast mass loss starts at temperatures above 420°C. Compound I exhibits photoluminescence at 430 nm (λex = 380 nm) with lifetimes of 5 and 12 ns and a quantum yield of 6% Текстовый файл AM_Agreement |
| Language: | English |
| Published: |
2025
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| Subjects: | |
| Online Access: | https://doi.org/10.1134/S1070328425600901 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=685412 |