Metal-Organic Framework [Cd2(Bdc)2Dabco]: Synthesis, Crystal Structure, and Photoluminescence Properties

Bibliographic Details
Parent link:	Russian Journal of Coordination Chemistry=Координационная химия.— .— Berlin: Springer Nature Vol. 51, iss. 8.— 2025.— P. 703-709
Other Authors:	Zaguzin A. S. Aleksandr Sergeevich, Zaytsev A. I. Aleksandr Ivanovich, Korobeynikov N. A. Nikita Alekseevich, Rakhmanova M. I. Mariana Ivanovna, Bondarenko M. A. Mikhail Aleksandrovich, Shurikov M. K. Matvey Konstantinovich, Fedin V. P. Vladimir Petrovich, Adonin S. A. Sergey Aleksandrovich
Summary:	Title screen The reaction of cadmium nitrate, terephthalic acid (Bdc), and 1,4-diazabicyclo[2.2.2]octane (Dabco) in N,N-dimethylformamide affords the new coordination polymer [Cd2(Bdc)2Dabco] (I), whose structure is determined by X-ray diffraction (CIF file CCDC no. 2441975). This coordination polymer (or metal-organic framework) demonstrates high thermal stability: the fast mass loss starts at temperatures above 420°C. Compound I exhibits photoluminescence at 430 nm (λex = 380 nm) with lifetimes of 5 and 12 ns and a quantum yield of 6% Текстовый файл AM_Agreement
Language:	English
Published:	2025
Subjects:	metal-organic frameworks carboxylate complexes cadmium luminescence properties труды учёных ТПУ электронный ресурс
Online Access:	https://doi.org/10.1134/S1070328425600901
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=685412

Description
Summary:	Title screen The reaction of cadmium nitrate, terephthalic acid (Bdc), and 1,4-diazabicyclo[2.2.2]octane (Dabco) in N,N-dimethylformamide affords the new coordination polymer [Cd2(Bdc)2Dabco] (I), whose structure is determined by X-ray diffraction (CIF file CCDC no. 2441975). This coordination polymer (or metal-organic framework) demonstrates high thermal stability: the fast mass loss starts at temperatures above 420°C. Compound I exhibits photoluminescence at 430 nm (λex = 380 nm) with lifetimes of 5 and 12 ns and a quantum yield of 6% Текстовый файл AM_Agreement
DOI:	10.1134/S1070328425600901

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