Evaluation of the Functional Suitability of Carboxylate Chlorin e6 Derivatives for Use in Radionuclide Diagnostics

Bibliographic Details
Parent link:Pharmaceutics.— .— Basel: MDPI AG
Vol. 18, iss. 1.— 2026.— Article number 23, 23 p.
Other Authors: Larkina M. S. Mariya Sergeevna, Demina A. Anastasia, Suvorov N. Nikita, Ostroverkhov P. Petr, Plotnikov E. V. Evgeny Vladimirovich, Varvashenya R. N. Ruslan Nikolaevich, Bodenko V. V. Vitalina Vasiljevna, Yanovich G. Gleb, Prach A. A. Anastasiya Aleksandrovna, Pogorilyy V. Viktor, Tikhonov S. Sergey, Popov A. Alexander, Usachev M. Maxim, Volel B. Beatrice, Vasil’ev Yu. Yuriy, Belousov M. Mikhail, Grin M. Mikhail
Summary:Radionuclide-based molecular imaging modalities are active and developing areas of functional and molecular diagnosis. Among the radionuclides used for SPECT imaging in oncology, 99mTc is a leading candidate for radiolabeling. At present, a sufficient number of complexons for 99mTc have been described; however, the development of effective delivery systems for this isotope to the area of interest is a complex research task. The use of tumor-targeting molecules as carriers for radioactive tracers is an effective strategy that has enabled the development of many novel radiopharmaceuticals for cancer imaging. Background: To date, a number of studies have shown tumorotropicity of tetrapyrrole compounds to tumor tissues, in particular derivatives of natural chlorophyll A. Methods: Purification was performed using solid-phase extraction. Assessment of radiochemical yield and purity was performed via radio-ITLC. The in vitro tumor cell accumulation was assessed using SKOV-3 and A-431 cell lines. Dose-dependent biodistribution was evaluated in Nu/J mice bearing epidermoid carcinoma (A-431) xenografts. Results: In this work, we obtained complexes with 99mTc based on water-soluble carboxylate chlorin e6 derivatives in order to evaluate their potential for use as SPECT radiopharmaceuticals. We performed radiolabelling optimization of a series of the novel chlorins and primary preclinical studies, including an assessment of the effect of their lipophilicity and charge on tumor uptake. Conclusions: Modification of the periphery of the chlorin macrocycle with chelating groups allows for complexing a wide range of metals, including 99mTc, which can be used for targeted delivery of the radionuclide to the area of interest
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Language:English
Published: 2026
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Online Access:https://doi.org/10.3390/pharmaceutics18010023
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=685391