Substituent effects on the structure of [Ag(py-R)n](NO3) ionic pairs: structural and computational studies; CrystEngComm; Vol. 27, iss. 48
| Parent link: | CrystEngComm.— .— London: Royal Society of Chemistry Vol. 27, iss. 48.— 2025.— 9 p. |
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| Další autoři: | , , , , , , , |
| Shrnutí: | Title screen Dissolution of AgNO3 in liquid pyridines (py-R) results in formation of [Ag(py-R)n](NO3) (n = 2, 3) complexes of different nature. Six complexes with py-R = pyridine (py), 2-methylpyridine (2-Mepy), 3-methylpyridine (3-Mepy), 4-methylpyridine (4-Mepy), 3,5-dimethylpyridine (3,5-Me2py), and 3-bromopyridine (3-Brpy) have been prepared and characterized by single crystal X-ray diffraction (SCXRD). The diffraction experiments were performed for i) crystals directly isolated from the mother liquor and ii) crystals of bulk samples stored after air-drying. The collected data show polymorphism or pyridine loss from [Ag(py-R)3](NO3) during the storage of bulk samples. The energies of Ag–N bonding inside the ionic pairs have been estimated by quantum-chemical calculations Текстовый файл AM_Agreement |
| Jazyk: | angličtina |
| Vydáno: |
2025
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| Témata: | |
| On-line přístup: | https://doi.org/10.1039/D5CE00829H |
| Médium: | Elektronický zdroj Kapitola |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=685138 |
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| 200 | 1 | |a Substituent effects on the structure of [Ag(py-R)n](NO3) ionic pairs: structural and computational studies |f Ekaterina A. Radiush, Gleb O. Sinelnikov, Matvey K. Shurikov [et al.] | |
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| 330 | |a Dissolution of AgNO3 in liquid pyridines (py-R) results in formation of [Ag(py-R)n](NO3) (n = 2, 3) complexes of different nature. Six complexes with py-R = pyridine (py), 2-methylpyridine (2-Mepy), 3-methylpyridine (3-Mepy), 4-methylpyridine (4-Mepy), 3,5-dimethylpyridine (3,5-Me2py), and 3-bromopyridine (3-Brpy) have been prepared and characterized by single crystal X-ray diffraction (SCXRD). The diffraction experiments were performed for i) crystals directly isolated from the mother liquor and ii) crystals of bulk samples stored after air-drying. The collected data show polymorphism or pyridine loss from [Ag(py-R)3](NO3) during the storage of bulk samples. The energies of Ag–N bonding inside the ionic pairs have been estimated by quantum-chemical calculations | ||
| 336 | |a Текстовый файл | ||
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| 461 | 1 | |t CrystEngComm |c London |n Royal Society of Chemistry | |
| 463 | 1 | |t Vol. 27, iss. 48 |v 9 p. |d 2025 | |
| 610 | 1 | |a электронный ресурс | |
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| 701 | 1 | |a Radyush |b E. A. |g Ekaterina Alekseevna | |
| 701 | 1 | |a Sinelnikov |b G. O. |g Gleb Olegovich | |
| 701 | 1 | |a Shurikov |b M. K. |c Chemist |c Laboratory assistant of Tomsk Polytechnic University |f 2000- |g Matvey Konstantinovich |9 22267 | |
| 701 | 1 | |a Shamshurin |b M. V. |g Maksim Vladimirovich | |
| 701 | 1 | |a Semenov |b N. A. |g Nikolay Aleksandrovich | |
| 701 | 1 | |a Postnikov |b P. S. |c organic chemist |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1984- |g Pavel Sergeevich |9 15465 | |
| 701 | 1 | |a Sokolov |b M. N. |g Maxim | |
| 701 | 1 | |a Abramov |b P. A. |c chemist |c professor, senior researcher at Tomsk Polytechnic University, Doctor of Chemical Sciences |f 1985- |g Pavel Aleksandrovich |9 88582 | |
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