Substituent effects on the structure of [Ag(py-R)n](NO3) ionic pairs: structural and computational studies

Bibliographic Details
Parent link:	CrystEngComm.— .— London: Royal Society of Chemistry Vol. 27, iss. 48.— 2025.— 9 p.
Other Authors:	Radyush E. A. Ekaterina Alekseevna, Sinelnikov G. O. Gleb Olegovich, Shurikov M. K. Matvey Konstantinovich, Shamshurin M. V. Maksim Vladimirovich, Semenov N. A. Nikolay Aleksandrovich, Postnikov P. S. Pavel Sergeevich, Sokolov M. N. Maxim, Abramov P. A. Pavel Aleksandrovich
Summary:	Title screen Dissolution of AgNO3 in liquid pyridines (py-R) results in formation of [Ag(py-R)n](NO3) (n = 2, 3) complexes of different nature. Six complexes with py-R = pyridine (py), 2-methylpyridine (2-Mepy), 3-methylpyridine (3-Mepy), 4-methylpyridine (4-Mepy), 3,5-dimethylpyridine (3,5-Me2py), and 3-bromopyridine (3-Brpy) have been prepared and characterized by single crystal X-ray diffraction (SCXRD). The diffraction experiments were performed for i) crystals directly isolated from the mother liquor and ii) crystals of bulk samples stored after air-drying. The collected data show polymorphism or pyridine loss from [Ag(py-R)3](NO3) during the storage of bulk samples. The energies of Ag–N bonding inside the ionic pairs have been estimated by quantum-chemical calculations Текстовый файл AM_Agreement
Language:	English
Published:	2025
Subjects:	электронный ресурс труды учёных ТПУ
Online Access:	https://doi.org/10.1039/D5CE00829H
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=685138

Internet

https://doi.org/10.1039/D5CE00829H