Improved spectroscopic parameters and rotational energy structure of the ground vibrational state of AsH3

Bibliographic Details
Parent link:Journal of Quantitative Spectroscopy and Radiative Transfer.— .— Amsterdam: Elsevier Science Publishing Company Inc.
Vol. 343.— 2025.— Article number 109496, 17 p.
Other Authors: Ulenekov (Ulenikov) O. N. Oleg Nikolaevich, Bekhtereva E. S. Elena Sergeevna, Gromova O. V. Olga Vasilievna, Sidko S. S. Sergey Sergeevich, Sydow Ch. Christian, Bauerekker (Bauerecker} Z. Kh. Zigurd Khermann
Summary:Title screen
The spectroscopic rotational, centrifugal distortion and splitting parameters as well as the rotational structure of the ground vibrational state of the AsH3 molecule are improved considerably in comparison with the analogous information known in the literature by new precise infrared FTIR experimental data and an improved effective Hamiltonian for a symmetric vibrational state of the C3v symmetry molecule. Compared with the corresponding results from previous studies, the results obtained in this study reproduce the original experimental parameters with more than ten times higher accuracy
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AM_Agreement
Language:English
Published: 2025
Subjects:
Online Access:https://doi.org/10.1016/j.jqsrt.2025.109496
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=680722