Sensitive electrochemical sensing of carbosulfan in food products on laser reduced graphene oxide sensor decorated with silver nanoparticles

Bibliographic Details
Parent link:Microchemical Journal.— .— Amsterdam: Elsevier Science Publishing Company Inc.
Vol. 207.— 2025.— Article number 112253, 14 p.
Other Authors: Saqib M. Muhammad, Dorozhko E. V. Elena Vladimirovna, Barek J. Jiri, Korotkova E. I. Elena Ivanovna, Semin V. O. Viktor Olegovich, Kolobova E. N. Ekaterina Nikolaevna, Erkovich A. V. Alina Vadimovna
Summary:Title screen
A simple, low-cost, eco-friendly, highly sensitive and selective electrochemical sensor based on laser reduced graphene oxide (LrGO) decorated with silver nanoparticles (LrGO/AgNPs) on a recycled green polyethylene terephthalate (PET) substrate was fabricated for the detection of carbosulfan in food products. An inexpensive disposable PET substrate was used to fabricate the flexible sensor using eco-friendly laser printing. Electrochemical investigations and surface characterization of sensor surfaces were performed with cyclic voltammetry (CV), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), Raman spectroscopy (RS), X-ray photoelectron spectroscopy (XPS), and electrochemical impedance spectroscopy (EIS). Under the optimum conditions, the LrGO/AgNPs sensor showed a well-developed CV peak current with a good linear dynamic range (LDR) from 0.01 to 10 mg·kg−1 for the determination of carbosulfan with a limit of detection (LOD) of 0.005 mg·kg−1. The LrGO/AgNPs sensor was successfully applied for CV determination of carbosulfan in food products (apples, oranges and basmati rice) with a promising recovery from 90 % to 105 % and relative standard deviations (RSD) lower than 5 %. The novel sensor showed remarkable sensitivity, selectivity, reproducibility, and long-term stability. Therefore, this study showed that the fabricated electrochemical LrGO/AgNPs sensor is an excellent tool for the determination of carbosulfan in food products
Текстовый файл
AM_Agreement
Language:English
Published: 2025
Subjects:
Online Access:https://doi.org/10.1016/j.microc.2024.112253
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=680062