Mild and General Protocol for Selective Deacetylation of Acetyl/Benzoyl-Protected Carbohydrates; Journal of Organic Chemistry; Vol. 89, iss.14

Mild and General Protocol for Selective Deacetylation of Acetyl/Benzoyl-Protected Carbohydrates; Journal of Organic Chemistry; Vol. 89, iss.14

Bibliografiska uppgifter
Parent link:Journal of Organic Chemistry.— .— Washington: American Chemical Society
Vol. 89, iss.14.— 2025.— P. 10021-10026
Övriga upphovsmän: Abramov A. A. Aleksandr Aleksandrovich, Zinin A. I. Aleksandr Ivanovich, Kolotyrkina N. G. Natalya, Kononov L. O., Shatskiy A. Andrey, Karkas M. D. Markus, Stepanova E. V. Elena Vladimirovna
Sammanfattning:Title screen
Herein, we report a mild and general protocol for chemoselective deacetylation of mixed acetyl- and benzoyl-protected carbohydrates under mild acidic conditions. The protocol allows quick access to partially protected carbohydrates, which serve as versatile synthetic intermediates during the total synthesis of various mono- and oligosaccharide targets. The applicability of the developed protocol was successfully demonstrated on a range of carbohydrate substrates of various configurations and substitution patterns featuring functionalized aliphatic and aromatic aglycones. The protocol has shown excellent compatibility with the widely used O-anomeric protecting groups, prespacer aglycones, and thioglycoside glycosyl donors
Текстовый файл
Språk:engelska
Publicerad: 2025
Ämnen:
электронный ресурс
труды учёных ТПУ
Carbohydrates
Chemical reactions
Free radicals
Organic compounds
Protective groups
Länkar:https://doi.org/10.1021/acs.joc.4c00900
Materialtyp: Elektronisk Bokavsnitt
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=680034

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