Mild and General Protocol for Selective Deacetylation of Acetyl/Benzoyl-Protected Carbohydrates; Journal of Organic Chemistry; Vol. 89, iss.14
| Parent link: | Journal of Organic Chemistry.— .— Washington: American Chemical Society Vol. 89, iss.14.— 2025.— P. 10021-10026 |
|---|---|
| Diğer Yazarlar: | Abramov A. A. Aleksandr Aleksandrovich, Zinin A. I. Aleksandr Ivanovich, Kolotyrkina N. G. Natalya, Kononov L. O., Shatskiy A. Andrey, Karkas M. D. Markus, Stepanova E. V. Elena Vladimirovna |
| Özet: | Title screen Herein, we report a mild and general protocol for chemoselective deacetylation of mixed acetyl- and benzoyl-protected carbohydrates under mild acidic conditions. The protocol allows quick access to partially protected carbohydrates, which serve as versatile synthetic intermediates during the total synthesis of various mono- and oligosaccharide targets. The applicability of the developed protocol was successfully demonstrated on a range of carbohydrate substrates of various configurations and substitution patterns featuring functionalized aliphatic and aromatic aglycones. The protocol has shown excellent compatibility with the widely used O-anomeric protecting groups, prespacer aglycones, and thioglycoside glycosyl donors Текстовый файл |
| Dil: | İngilizce |
| Baskı/Yayın Bilgisi: |
2025
|
| Konular: | |
| Online Erişim: | https://doi.org/10.1021/acs.joc.4c00900 |
| Materyal Türü: | Elektronik Kitap Bölümü |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=680034 |
Benzer Materyaller
Synthesis of Salicaceae Acetyl Salicins Using Selective Deacetylation and Acetyl Group Migration; Journal of Natural Products; Vol. 83, iss. 4
Baskı/Yayın Bilgisi: (2020)
Baskı/Yayın Bilgisi: (2020)
Azidation of Partially Protected Carbohydrate Derivatives: Efficient Suppression of Acyl Migration; Synlett; Vol. 31, № 15
Baskı/Yayın Bilgisi: (2020)
Baskı/Yayın Bilgisi: (2020)
A new look at acid catalyzed deacetylation of carbohydrates: A regioselective synthesis and reactivity of 2-O-acetyl aryl glycopyranosides; Carbohydrate Research; Vol. 458-459
Baskı/Yayın Bilgisi: (2018)
Baskı/Yayın Bilgisi: (2018)
Effect of Nitrogen Arc Discharge Plasma Treatment on Physicochemical Properties and Biocompatibility of PLA-Based Scaffolds; Polymers; Vol. 15, iss. 16
Baskı/Yayın Bilgisi: (2023)
Baskı/Yayın Bilgisi: (2023)
Regioselective deacetylation of peracetylated glycosides with a cleavable aglycone; Carbohydrate Research; Vol. 556
Baskı/Yayın Bilgisi: (2025)
Baskı/Yayın Bilgisi: (2025)
The development of liquid-phase method for phenol deep oxidation; Bulletin of the Tomsk Polytechnic University; Vol. 311, № 3
Yazar:: Kukurina O. S. Olga Sergeevna
Baskı/Yayın Bilgisi: (2007)
Yazar:: Kukurina O. S. Olga Sergeevna
Baskı/Yayın Bilgisi: (2007)
Antioxidant Properties of New Phenothiazine Derivatives; Antioxidants; Vol. 11, iss. 7
Baskı/Yayın Bilgisi: (2022)
Baskı/Yayın Bilgisi: (2022)
Exploiting photoredox catalysis for carbohydrate modification through C–H and C–C bond activation; Nature Reviews Chemistry; Vol. 6, iss. 11
Yazar:: Shatskiy A. Andrey
Baskı/Yayın Bilgisi: (2022)
Yazar:: Shatskiy A. Andrey
Baskı/Yayın Bilgisi: (2022)
Effect of Native Humic Acids from Tomsk Region Lowland Peat on Mitochrondrial Oxidative Phosphorylation Under Hypoxic Conditions; Pharmaceutical Chemistry Journal; Vol. 49, iss. 4
Baskı/Yayın Bilgisi: (2015)
Baskı/Yayın Bilgisi: (2015)
The chemistry of heterocycles in the 21st century; Russian Chemical Reviews; Vol. 93, iss. 7
Baskı/Yayın Bilgisi: (2024)
Baskı/Yayın Bilgisi: (2024)
Preparation and X‑ray Structural Study of Dibenzobromolium and Dibenzochlorolium Derivatives; ACS Omega; Vol. 9 - iss. 2
Baskı/Yayın Bilgisi: (2024)
Baskı/Yayın Bilgisi: (2024)
Two-level model of composite synthesis on a substrate from a powder mixture of TiO2 and Al2 structure of the reaction zone in a two-level model of coating synthesis; Nanoscience and Technology: An International Journal; Vol. 15, iss. 3
Yazar:: Anisimova M. A. Mariya Aleksandrovna
Baskı/Yayın Bilgisi: (2024)
Yazar:: Anisimova M. A. Mariya Aleksandrovna
Baskı/Yayın Bilgisi: (2024)
Interaction of substituted aril iodide with protonic acid; Bulletin of the Tomsk Polytechnic University; Vol. 310, № 1
Baskı/Yayın Bilgisi: (2007)
Baskı/Yayın Bilgisi: (2007)
A novel impedimetric sensor based on N-acetyl-L-cysteine for the determination of hydroxyl radicals in cell cultures in vitro; Talanta; Vol. 270
Baskı/Yayın Bilgisi: (2024)
Baskı/Yayın Bilgisi: (2024)
An N-Acetyl-L-Cysteine Impedance Sensor for Assessing Antioxidant Activity against Hydroxyl Radicals; Journal of Analytical Chemistry; Vol. 79, iss. 6
Baskı/Yayın Bilgisi: (2024)
Baskı/Yayın Bilgisi: (2024)
Features of the Synthesis of TiCAl (Fe2O3/TiO2) Metal Matrix Composites under Nonequilibrium Conditions; Energy Fluxes and Radiation Effects (EFRE-2020 online)
Yazar:: Knyazeva A. G. Anna Georgievna
Baskı/Yayın Bilgisi: (2020)
Yazar:: Knyazeva A. G. Anna Georgievna
Baskı/Yayın Bilgisi: (2020)
Peculiarities of sludge formation and composition of oil paraffin carbohydrates in the Upper-Salat deposit; Bulletin of the Tomsk Polytechnic University; Vol. 310, № 2
Baskı/Yayın Bilgisi: (2007)
Baskı/Yayın Bilgisi: (2007)
Pulsed Corona Discharge Induced Hydroxyl Radical Transfer Through the Gas-Liquid Interface; Scientific Reports; Vol. 7
Yazar:: Ajo P. Petri
Baskı/Yayın Bilgisi: (2017)
Yazar:: Ajo P. Petri
Baskı/Yayın Bilgisi: (2017)
Choice of the Kinetic Scheme of Oxidation Reactions of the Gaseous Products of Coal Pyrolysis during Induction Period at Ignition of the Water–Coal Fuel Particles; Energy and Fuels; Vol. 33, iss. 11
Baskı/Yayın Bilgisi: (2019)
Baskı/Yayın Bilgisi: (2019)
2,4,5,6-Substituted 4,5-dihydro-1,2,4,5-tetrazin-3(2H)-ones as non-classical initiators of controlled radical polymerization of styrene; Russian Chemical Bulletin; Vol. 71, iss. 7
Baskı/Yayın Bilgisi: (2022)
Baskı/Yayın Bilgisi: (2022)
Thermodynamic and Technological Studies of the Electric Smelting of Satpaevsk Ilmenite Concentrates; Metals; Vol. 14, iss. 11
Baskı/Yayın Bilgisi: (2024)
Baskı/Yayın Bilgisi: (2024)
Mathematical simulation of deciduous tree ignition by cloud-to-ground lightning discharge using large vessels approximation; JP Journal of Heat and Mass Transfer; Vol. 14, iss. 4
Yazar:: Baranovskiy N. V. Nikolay Viktorovich
Baskı/Yayın Bilgisi: (2017)
Yazar:: Baranovskiy N. V. Nikolay Viktorovich
Baskı/Yayın Bilgisi: (2017)
Пространственная постановка задачи о зажигании хвойного дерева наземным грозовым разрядом; Пожаровзрывобезопасность; Т. 19, № 10
Yazar:: Барановский Н. В. Николай Викторович
Baskı/Yayın Bilgisi: (2010)
Yazar:: Барановский Н. В. Николай Викторович
Baskı/Yayın Bilgisi: (2010)
Пространственная постановка и численное исследование задачи о зажигании лиственного дерева наземным грозовым разрядом; Бутлеровские сообщения; Т. 24, № 1
Yazar:: Кузнецов Г. В. Гений Владимирович
Baskı/Yayın Bilgisi: (2011)
Yazar:: Кузнецов Г. В. Гений Владимирович
Baskı/Yayın Bilgisi: (2011)
Пространственная постановка и численное исследование задачи о зажигании слоя лесного горючего материала нагретой до высоких температур частицей; Бутлеровские сообщения; Т. 22, № 12
Yazar:: Кузнецов Г. В. Гений Владимирович
Baskı/Yayın Bilgisi: (2010)
Yazar:: Кузнецов Г. В. Гений Владимирович
Baskı/Yayın Bilgisi: (2010)
Ionization Processes in a Carbon Aerosol Upon Exposure to Long Laser Pulses. II; Russian Physics Journal; Vol. 65, iss. 4
Baskı/Yayın Bilgisi: (2022)
Baskı/Yayın Bilgisi: (2022)
Ionization Processes in a Carbon Aerosol Upon Exposure to Long Laser Pulses. I; Russian Physics Journal; Vol. 65, iss. 2
Baskı/Yayın Bilgisi: (2022)
Baskı/Yayın Bilgisi: (2022)
Исследование физико-химических процессов зажигания хвойного дерева наземным грозовым разрядом; Бутлеровские сообщения; Т. 20, № 6
Yazar:: Кузнецов Г. В. Гений Владимирович
Baskı/Yayın Bilgisi: (2010)
Yazar:: Кузнецов Г. В. Гений Владимирович
Baskı/Yayın Bilgisi: (2010)
Hygroscopic Properties of Industrial Aluminum Powders; Russian Journal of Physical Chemistry A; Vol. 99, iss. 9
Yazar:: Tereshchenko A. G. Anatoly Georgievich
Baskı/Yayın Bilgisi: (2025)
Yazar:: Tereshchenko A. G. Anatoly Georgievich
Baskı/Yayın Bilgisi: (2025)
Plasma-Chemical Deposition of Anti-Reflection and Protective Coating for Infrared Optics; Russian Physics Journal; Vol. 62, iss. 11
Baskı/Yayın Bilgisi: (2020)
Baskı/Yayın Bilgisi: (2020)
Химическая термодинамика фторидно-аммониевой переработки золошлаковых техногенных отходов; Известия Томского политехнического университета [Известия ТПУ]. Инжиниринг георесурсов; Т. 335, № 12
Baskı/Yayın Bilgisi: (2024)
Baskı/Yayın Bilgisi: (2024)
Детерминированная компонента методики прогноза лесной пожарной опасности по неустановленным причинам; Пожаровзрывобезопасность; Т. 20, № 11
Yazar:: Кузнецов Г. В. Гений Владимирович
Baskı/Yayın Bilgisi: (2011)
Yazar:: Кузнецов Г. В. Гений Владимирович
Baskı/Yayın Bilgisi: (2011)
Degradation of Nitride Coatings in Low-Pressure Gas Discharge Plasma; AIP Conference Proceedings; Vol. 1909 : Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures 2017 (AMHS’17)
Baskı/Yayın Bilgisi: (2017)
Baskı/Yayın Bilgisi: (2017)
About Structural Phase State of Coating Based on Zirconium Oxide Formed by Microplasma Oxidation Method; AIP Conference Proceedings; Vol. 1909 : Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures 2017 (AMHS’17)
Baskı/Yayın Bilgisi: (2017)
Baskı/Yayın Bilgisi: (2017)
Антипирены для обработки древесины; Прогрессивные технологии и экономика в машиностроении
Yazar:: Эшмухамедова М. Р.
Baskı/Yayın Bilgisi: (2021)
Yazar:: Эшмухамедова М. Р.
Baskı/Yayın Bilgisi: (2021)
Thermal conditions of the battery cell of an electrochemical energy storage system under intense electrochemical and chemical reactions; Journal of the Brazilian Society of Mechanical Sciences and Engineering; Vol. 47
Yazar:: Kuznetsov G. V. Geny Vladimirovich
Baskı/Yayın Bilgisi: (2025)
Yazar:: Kuznetsov G. V. Geny Vladimirovich
Baskı/Yayın Bilgisi: (2025)
Coniferous Tree Ignition by Cloud-to-Ground Lightning Discharge Using Approximation of "Ideal" Crack in Bark; JP Journal of Heat and Mass Transfer; Vol. 14, iss. 1
Yazar:: Baranovskiy N. V. Nikolay Viktorovich
Baskı/Yayın Bilgisi: (2016)
Yazar:: Baranovskiy N. V. Nikolay Viktorovich
Baskı/Yayın Bilgisi: (2016)
Modelling of transition zone formation between thin Si or Ta film deposited on TiNi under low-energy electron beam irradiation; Materials Research Express; Vol. 6, iss. 10
Yazar:: Knyazeva A. G. Anna Georgievna
Baskı/Yayın Bilgisi: (2019)
Yazar:: Knyazeva A. G. Anna Georgievna
Baskı/Yayın Bilgisi: (2019)
Aromaticity of charged cyclocarbon radicals (Cn± = 6–30); Chemical Physics Letters; Vol. 858
Baskı/Yayın Bilgisi: (2024)
Baskı/Yayın Bilgisi: (2024)
Spatial Distribution of Chemical and Organic Compounds in the Water of Oligotrophic Peatland of Tomsk Region (Western Siberia); Procedia Chemistry; Vol. 10 : Chemistry and Chemical Engineering in XXI century
Baskı/Yayın Bilgisi: (2014)
Baskı/Yayın Bilgisi: (2014)
Benzer Materyaller
-
Synthesis of Salicaceae Acetyl Salicins Using Selective Deacetylation and Acetyl Group Migration; Journal of Natural Products; Vol. 83, iss. 4
Baskı/Yayın Bilgisi: (2020) -
Azidation of Partially Protected Carbohydrate Derivatives: Efficient Suppression of Acyl Migration; Synlett; Vol. 31, № 15
Baskı/Yayın Bilgisi: (2020) -
A new look at acid catalyzed deacetylation of carbohydrates: A regioselective synthesis and reactivity of 2-O-acetyl aryl glycopyranosides; Carbohydrate Research; Vol. 458-459
Baskı/Yayın Bilgisi: (2018) -
Effect of Nitrogen Arc Discharge Plasma Treatment on Physicochemical Properties and Biocompatibility of PLA-Based Scaffolds; Polymers; Vol. 15, iss. 16
Baskı/Yayın Bilgisi: (2023) -
Regioselective deacetylation of peracetylated glycosides with a cleavable aglycone; Carbohydrate Research; Vol. 556
Baskı/Yayın Bilgisi: (2025)