Cr3+-doped MgAl2O4 spinel ceramics fabricated by arc plasma melting method; Ceramics International; Vol. 51, iss. 16, Pt. 1

Detalles Bibliográficos
Parent link:Ceramics International.— .— Amsterdam: Elsevier Science Publishing Company Inc.
Vol. 51, iss. 16, Pt. 1.— 2025.— P. 21546-21553
Otros Autores: Valiev D. T. Damir Talgatovich, Shekhovtsov V. V. Valentin Vladimirovich, Sharafeev Sh. M. Sharif Mnirovich, Stepanov S. A. Sergey Aleksandrovich
Sumario:Title screen
The arc plasma synthesis method was employed to produce the MgAl2O4:xCr3+ (x = 0.01–1 wt%) luminescent ceramics. Structural (XRD), morphological (SEM, optical microscopy) and spectroscopic analyses were conducted to investigate the influence of Cr2O3 concentration on the phase composition of ceramics, the unit cell parameters of MgAl2O4:Cr3+ and their luminescent properties. It was established that the formation of spinel occurs within just 5 s of arc plasma synthesis, while the time required to complete melting and the production of a hemispherical spinel product is 25–30 s. Increasing the Cr2O3 concentration up to 0.25 wt % enhances the photoluminescence efficiency, after which a gradual decrease is observed. The relationship between photoluminescence (PL) efficiency and temperature was also indicated. This study demonstrates that the arc plasma melting method has potential for the rapid synthesis of MgAl2O4:Cr3+ luminescent ceramics
Текстовый файл
AM_Agreement
Lenguaje:inglés
Publicado: 2025
Materias:
Acceso en línea:https://doi.org/10.1016/j.ceramint.2025.02.315
Formato: Electrónico Capítulo de libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=679089

MARC

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330 |a The arc plasma synthesis method was employed to produce the MgAl2O4:xCr3+ (x = 0.01–1 wt%) luminescent ceramics. Structural (XRD), morphological (SEM, optical microscopy) and spectroscopic analyses were conducted to investigate the influence of Cr2O3 concentration on the phase composition of ceramics, the unit cell parameters of MgAl2O4:Cr3+ and their luminescent properties. It was established that the formation of spinel occurs within just 5 s of arc plasma synthesis, while the time required to complete melting and the production of a hemispherical spinel product is 25–30 s. Increasing the Cr2O3 concentration up to 0.25 wt % enhances the photoluminescence efficiency, after which a gradual decrease is observed. The relationship between photoluminescence (PL) efficiency and temperature was also indicated. This study demonstrates that the arc plasma melting method has potential for the rapid synthesis of MgAl2O4:Cr3+ luminescent ceramics 
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463 1 |t Vol. 51, iss. 16, Pt. 1  |v P. 21546-21553  |d 2025 
610 1 |a MgAl2O4 spinel ceramics 
610 1 |a Thermal plasma 
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610 1 |a Luminescence 
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701 1 |a Valiev  |b D. T.  |c specialist in the field of material science  |c Associate Professor of Tomsk Polytechnic University, Candidate of Physical and Mathematical Sciences  |f 1987-  |g Damir Talgatovich  |9 17370 
701 1 |a Shekhovtsov  |b V. V.  |g Valentin Vladimirovich 
701 1 |a Sharafeev  |b Sh. M.  |c chemical engineer  |c Engineer of Tomsk Polytechnic University, Candidate of Technical Sciences  |f 1994-  |g Sharif Mnirovich  |9 22455 
701 1 |a Stepanov  |b S. A.  |c specialist in the field of lightning engineering  |c Engineer of Tomsk Polytechnic University  |f 1986-  |g Sergey Aleksandrovich  |9 17369 
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