Access to Carbonyl Azides via Iodine(III)-Mediated Cross-Coupling; Organic Letters; Vol. 26, iss. 43
| Parent link: | Organic Letters.— .— Washington: ACS Publications Vol. 26, iss. 43.— 2024.— P. 9215–9220 |
|---|---|
| Daljnji autori: | Qing Yan, Lanlan Lv, Li Xu, Stepanova E. V. Elena Vladimirovna, Alvey G. R. Gregory, Shatskiy A. Andrey, Kärkäs M. D. Markus, Xiang-Shan Wang |
| Sažetak: | Title screen Herein, we present a prominent metal-free C–N cross-coupling platform that enables access to carbamoyl- and ketoazides from isocyanides or silyl enol ethers and trimethylsilyl azide (TMSN3) with an aid of iodine(III) promoter. This offers a rapid route to a diverse set of synthetically valuable azide decorated fragments with excellent substrate scope and good to excellent yields. The disclosed platform exemplifies the use of TMSN3 for incorporation of the azide fragment without the loss of N2 Текстовый файл AM_Agreement |
| Jezik: | engleski |
| Izdano: |
2024
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| Teme: | |
| Online pristup: | https://doi.org/10.1021/acs.orglett.4c03212 |
| Format: | Elektronički Poglavlje knjige |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=678619 |
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Hypervalent Iodine(III) Reagent Mediated Regioselective Cycloaddition of Aldoximes with Enaminones; European Journal of Organic Chemistry; Vol. 2019, iss. 39
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