Access to Carbonyl Azides via Iodine(III)-Mediated Cross-Coupling; Organic Letters; Vol. 26, iss. 43

Bibliografski detalji
Parent link:Organic Letters.— .— Washington: ACS Publications
Vol. 26, iss. 43.— 2024.— P. 9215–9220
Daljnji autori: Qing Yan, Lanlan Lv, Li Xu, Stepanova E. V. Elena Vladimirovna, Alvey G. R. Gregory, Shatskiy A. Andrey, Kärkäs M. D. Markus, Xiang-Shan Wang
Sažetak:Title screen
Herein, we present a prominent metal-free C–N cross-coupling platform that enables access to carbamoyl- and ketoazides from isocyanides or silyl enol ethers and trimethylsilyl azide (TMSN3) with an aid of iodine(III) promoter. This offers a rapid route to a diverse set of synthetically valuable azide decorated fragments with excellent substrate scope and good to excellent yields. The disclosed platform exemplifies the use of TMSN3 for incorporation of the azide fragment without the loss of N2
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AM_Agreement
Jezik:engleski
Izdano: 2024
Teme:
Online pristup:https://doi.org/10.1021/acs.orglett.4c03212
Format: Elektronički Poglavlje knjige
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=678619

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