Access to Carbonyl Azides via Iodine(III)-Mediated Cross-Coupling

Bibliographic Details
Parent link:	Organic Letters.— .— Washington: ACS Publications Vol. 26, iss. 43.— 2024.— P. 9215–9220
Other Authors:	Qing Yan, Lanlan Lv, Li Xu, Stepanova E. V. Elena Vladimirovna, Alvey G. R. Gregory, Shatskiy A. Andrey, Kärkäs M. D. Markus, Xiang-Shan Wang
Summary:	Title screen Herein, we present a prominent metal-free C–N cross-coupling platform that enables access to carbamoyl- and ketoazides from isocyanides or silyl enol ethers and trimethylsilyl azide (TMSN3) with an aid of iodine(III) promoter. This offers a rapid route to a diverse set of synthetically valuable azide decorated fragments with excellent substrate scope and good to excellent yields. The disclosed platform exemplifies the use of TMSN3 for incorporation of the azide fragment without the loss of N2 Текстовый файл AM_Agreement
Language:	English
Published:	2024
Subjects:	труды учёных ТПУ электронный ресурс
Online Access:	https://doi.org/10.1021/acs.orglett.4c03212
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=678619

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