Access to Carbonyl Azides via Iodine(III)-Mediated Cross-Coupling
| Parent link: | Organic Letters.— .— Washington: ACS Publications Vol. 26, iss. 43.— 2024.— P. 9215–9220 |
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| अन्य लेखक: | , , , , , , , |
| सारांश: | Title screen Herein, we present a prominent metal-free C–N cross-coupling platform that enables access to carbamoyl- and ketoazides from isocyanides or silyl enol ethers and trimethylsilyl azide (TMSN3) with an aid of iodine(III) promoter. This offers a rapid route to a diverse set of synthetically valuable azide decorated fragments with excellent substrate scope and good to excellent yields. The disclosed platform exemplifies the use of TMSN3 for incorporation of the azide fragment without the loss of N2 Текстовый файл AM_Agreement |
| भाषा: | अंग्रेज़ी |
| प्रकाशित: |
2024
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| विषय: | |
| ऑनलाइन पहुंच: | https://doi.org/10.1021/acs.orglett.4c03212 |
| स्वरूप: | इलेक्ट्रोनिक पुस्तक अध्याय |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=678619 |
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| 200 | 1 | |a Access to Carbonyl Azides via Iodine(III)-Mediated Cross-Coupling |f Qing Yan, Lanlan Lv, Li Xu [et al.] | |
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| 330 | |a Herein, we present a prominent metal-free C–N cross-coupling platform that enables access to carbamoyl- and ketoazides from isocyanides or silyl enol ethers and trimethylsilyl azide (TMSN3) with an aid of iodine(III) promoter. This offers a rapid route to a diverse set of synthetically valuable azide decorated fragments with excellent substrate scope and good to excellent yields. The disclosed platform exemplifies the use of TMSN3 for incorporation of the azide fragment without the loss of N2 | ||
| 336 | |a Текстовый файл | ||
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| 461 | 1 | |t Organic Letters |c Washington |n ACS Publications | |
| 463 | 1 | |t Vol. 26, iss. 43 |v P. 9215–9220 |d 2024 | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a электронный ресурс | |
| 701 | 0 | |a Qing Yan | |
| 701 | 0 | |a Lanlan Lv | |
| 701 | 0 | |a Li Xu | |
| 701 | 1 | |a Stepanova |b E. V. |c chemist |c Associate Professor of Tomsk Polytechnic University, Candidate of Chemical Sciences |f 1988- |g Elena Vladimirovna |9 17776 | |
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