First comprehensive high resolution study of the 28SiH octad bending bands; Journal of Quantitative Spectroscopy and Radiative Transfer; Vol. 331

First comprehensive high resolution study of the 28SiH octad bending bands; Journal of Quantitative Spectroscopy and Radiative Transfer; Vol. 331

Bibliografski detalji
Parent link:Journal of Quantitative Spectroscopy and Radiative Transfer.— .— Amsterdam: Elsevier Science Publishing Company Inc.
Vol. 331.— 2025.— Article number 109259, 11 p.
Daljnji autori: Ulenekov (Ulenikov) O. N. Oleg Nikolaevich, Gromova O. V. Olga Vasilievna, Bekhtereva E. S. Elena Sergeevna, Nikolaeva N. I. Natalya Ivanovna, Sydow C. Christian, Bauerekker (Bauerekker) Z. Kh. Zigurd Khermann
Sažetak:Title screen
The infrared spectrum of mono-silane was measured at varied experimental conditions with a Bruker Fourier transform infrared spectrometer IFS125HR and analyzed for the first time in the 2600–2950 cm−1 region of the octad where 16 strongly interacting triply excited bending bands are located. The 3505 transitions belonging to fourteen sub-bands of the octad (with the exception of unappeared 3ν4(A1) and 3ν2(A2)) were assigned (Jmax=20) and theoretically analyzed in the frame of the effective Hamiltonian model. The obtained set of 139 fitted parameters reproduces the initial 3505 experimental line positions with the drms=7.3×10−4 cm−4. A list of assigned experimental transitions is presented as the Supplementary data 2 to this paper
Текстовый файл
AM_Agreement
Jezik:engleski
Izdano: 2025
Teme:
электронный ресурс
труды учёных ТПУ
infrared spectrum
effective Hamiltonian model
Online pristup:https://doi.org/10.1016/j.jqsrt.2024.109259
Format: Elektronički Poglavlje knjige
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=678256

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