First comprehensive high resolution study of the 28SiH octad bending bands
| Parent link: | Journal of Quantitative Spectroscopy and Radiative Transfer.— .— Amsterdam: Elsevier Science Publishing Company Inc. Vol. 331.— 2025.— Article number 109259, 11 p. |
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| Other Authors: | , , , , , |
| Summary: | Title screen The infrared spectrum of mono-silane was measured at varied experimental conditions with a Bruker Fourier transform infrared spectrometer IFS125HR and analyzed for the first time in the 2600–2950 cm−1 region of the octad where 16 strongly interacting triply excited bending bands are located. The 3505 transitions belonging to fourteen sub-bands of the octad (with the exception of unappeared 3ν4(A1) and 3ν2(A2)) were assigned (Jmax=20) and theoretically analyzed in the frame of the effective Hamiltonian model. The obtained set of 139 fitted parameters reproduces the initial 3505 experimental line positions with the drms=7.3×10−4 cm−4. A list of assigned experimental transitions is presented as the Supplementary data 2 to this paper Текстовый файл AM_Agreement |
| Published: |
2025
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| Subjects: | |
| Online Access: | https://doi.org/10.1016/j.jqsrt.2024.109259 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=678256 |