Pseudocyclic Arylbenziodoxaboroles as Water-Triggered Aryne Precursors in Reactions with Organic Sulfides

Pseudocyclic Arylbenziodoxaboroles as Water-Triggered Aryne Precursors in Reactions with Organic Sulfides

Bibliografiske detaljer
Parent link:	Organic Letters.— .— Washington: ACS Publications Vol. 26, iss. 9.— 2024.— P. 1891-1895
Institution som forfatter:	National Research Tomsk Polytechnic University
Andre forfattere:	Yoshimura A. Akira, Kim Ngo, Mironova I. A. Irina Andreevna, Gardner Z. S. Zachary, Rohde G. T. Gregory, Nami Ogura, Ueki A. Akiharu, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Saito A. Akio, Zhdankin V. V. Viktor Vladimirovich
Summary:	Title screen Pseudocyclic arylbenziodoxaboroles are unique aryne precursors under neutral aqueous conditions that selectively react with organic sulfides, forming the corresponding sulfonium salts. This reaction is compatible with various substituents (alkyl, halogen, CN, NO2, CHO, and cyclopropyl) in the aromatic ring or alkyl group of the sulfide. Similar reactions of sulfoxides afford o-hydroxy-substituted sulfonium salts. The structures of key products were confirmed by X-ray analysis. Текстовый файл
Udgivet:	2024
Fag:	труды учёных ТПУ электронный ресурс
Online adgang:	https://doi.org/10.1021/acs.orglett.4c00197
Format:	Electronisk Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=672080

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