Pseudocyclic Arylbenziodoxaboroles as Water-Triggered Aryne Precursors in Reactions with Organic Sulfides
| Parent link: | Organic Letters.— .— Washington: ACS Publications Vol. 26, iss. 9.— 2024.— P. 1891-1895 |
|---|---|
| Institutionell upphovsman: | National Research Tomsk Polytechnic University |
| Övriga upphovsmän: | Yoshimura A. Akira, Kim Ngo, Mironova I. A. Irina Andreevna, Gardner Z. S. Zachary, Rohde G. T. Gregory, Nami Ogura, Ueki A. Akiharu, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Saito A. Akio, Zhdankin V. V. Viktor Vladimirovich |
| Sammanfattning: | Title screen Pseudocyclic arylbenziodoxaboroles are unique aryne precursors under neutral aqueous conditions that selectively react with organic sulfides, forming the corresponding sulfonium salts. This reaction is compatible with various substituents (alkyl, halogen, CN, NO2, CHO, and cyclopropyl) in the aromatic ring or alkyl group of the sulfide. Similar reactions of sulfoxides afford o-hydroxy-substituted sulfonium salts. The structures of key products were confirmed by X-ray analysis. Текстовый файл |
| Språk: | engelska |
| Publicerad: |
2024
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| Ämnen: | |
| Länkar: | https://doi.org/10.1021/acs.orglett.4c00197 |
| Materialtyp: | Elektronisk Bokavsnitt |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=672080 |
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