Pseudocyclic Arylbenziodoxaboroles as Water-Triggered Aryne Precursors in Reactions with Organic Sulfides

Detalhes bibliográficos
Parent link:	Organic Letters.— .— Washington: ACS Publications Vol. 26, iss. 9.— 2024.— P. 1891-1895
Autor Corporativo:	National Research Tomsk Polytechnic University
Outros Autores:	Yoshimura A. Akira, Kim Ngo, Mironova I. A. Irina Andreevna, Gardner Z. S. Zachary, Rohde G. T. Gregory, Nami Ogura, Ueki A. Akiharu, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Saito A. Akio, Zhdankin V. V. Viktor Vladimirovich
Resumo:	Title screen Pseudocyclic arylbenziodoxaboroles are unique aryne precursors under neutral aqueous conditions that selectively react with organic sulfides, forming the corresponding sulfonium salts. This reaction is compatible with various substituents (alkyl, halogen, CN, NO2, CHO, and cyclopropyl) in the aromatic ring or alkyl group of the sulfide. Similar reactions of sulfoxides afford o-hydroxy-substituted sulfonium salts. The structures of key products were confirmed by X-ray analysis. Текстовый файл
Publicado em:	2024
Assuntos:	труды учёных ТПУ электронный ресурс
Acesso em linha:	https://doi.org/10.1021/acs.orglett.4c00197
Formato:	Recurso Electrónico Capítulo de Livro
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=672080

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