Pseudocyclic Arylbenziodoxaboroles as Water-Triggered Aryne Precursors in Reactions with Organic Sulfides

Bibliographic Details
Parent link:	Organic Letters.— .— Washington: ACS Publications Vol. 26, iss. 9.— 2024.— P. 1891-1895
Corporate Author:	National Research Tomsk Polytechnic University
Other Authors:	Yoshimura A. Akira, Kim Ngo, Mironova I. A. Irina Andreevna, Gardner Z. S. Zachary, Rohde G. T. Gregory, Nami Ogura, Ueki A. Akiharu, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Saito A. Akio, Zhdankin V. V. Viktor Vladimirovich
Summary:	Title screen Pseudocyclic arylbenziodoxaboroles are unique aryne precursors under neutral aqueous conditions that selectively react with organic sulfides, forming the corresponding sulfonium salts. This reaction is compatible with various substituents (alkyl, halogen, CN, NO2, CHO, and cyclopropyl) in the aromatic ring or alkyl group of the sulfide. Similar reactions of sulfoxides afford o-hydroxy-substituted sulfonium salts. The structures of key products were confirmed by X-ray analysis. Текстовый файл
Language:	English
Published:	2024
Subjects:	труды учёных ТПУ электронный ресурс
Online Access:	https://doi.org/10.1021/acs.orglett.4c00197
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=672080

Description
Summary:	Title screen Pseudocyclic arylbenziodoxaboroles are unique aryne precursors under neutral aqueous conditions that selectively react with organic sulfides, forming the corresponding sulfonium salts. This reaction is compatible with various substituents (alkyl, halogen, CN, NO2, CHO, and cyclopropyl) in the aromatic ring or alkyl group of the sulfide. Similar reactions of sulfoxides afford o-hydroxy-substituted sulfonium salts. The structures of key products were confirmed by X-ray analysis. Текстовый файл
DOI:	10.1021/acs.orglett.4c00197

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