Investigation of interactions in the mechanically activated a-Fe2O3/Li2CO3 reagents by thermal analysis

Bibliographic Details
Parent link:Journal of Thermal Analysis and Calorimetry
Vol. 148.— 2023.— [P. 1581-1588]
Corporate Authors: Национальный исследовательский Томский политехнический университет Институт неразрушающего контроля Проблемная научно-исследовательская лаборатория электроники, диэлектриков и полупроводников, Национальный исследовательский Томский политехнический университет Инженерная школа неразрушающего контроля и безопасности Отделение контроля и диагностики
Other Authors: Nikolaev E. V. Evgeny Vladimirovich, Lysenko E. N. Elena Nikolaevna, Surzhikov A. P. Anatoly Petrovich, Elkin V. D. Vladimir Denisovich
Summary:Title screen
The paper addresses the study of the effect of different milling modes on the reactivity of the initial a-Fe2O3 and Li2CO3 powders by thermogravimetry and differential scanning calorimetry to obtain lithium ferrite of Li0.5Fe2.5O4 chemical composition. The formation of the magnetic phase of ferrite was monitored by thermogravimetric analysis in a magnetic field. The powder mixture was mechanically activated in air at different processing time and vial rotation speed using a planetary mill. It was found that the reactivity of the initial reagents depends on milling energy intensity. A varied milling mode changes the pattern of the interaction between reagents, and therefore a temperature range, the number of stages and the rate of lithium ferrite formation. In these conditions, an increased vial rotation speed during milling makes a more significant contribution to the change in the powder reactivity as compared to longer milling time.
Режим доступа: по договору с организацией-держателем ресурса
Published: 2023
Subjects:
Online Access:https://doi.org/10.1007/s10973-022-11412-6
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=669172