Preparation, Structure, and Reactivity of Pseudocyclic β-Trifluorosulfonyloxy Vinylbenziodoxolone Derivatives

Preparation, Structure, and Reactivity of Pseudocyclic β-Trifluorosulfonyloxy Vinylbenziodoxolone Derivatives

מידע ביבליוגרפי
Parent link:	Advanced Synthesis and Catalysis Vol. 363, iss. 13.— 2021.— [P. 3365-3371]
מחבר תאגידי:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
מחברים אחרים:	Yoshimura A. Akira, Huss Ch. D. Christopher, Mackenzie L. Liebl, Rohde G. L. Gregory, Larson S. M. Scott, Frahm G. B. Gunnar, Mattew W. L. W. Luedtke, Tanner J. Sh. J. Schumacher, Gardner S., Zhdankin V. V. Viktor Vladimirovich, Postnikov P. S. Pavel Sergeevich, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Tsugio K. Kitamura, Saito A. Akio
סיכום:	Title screen Pseudocyclic β-trifluorosulfonyloxy vinylbenziodoxolones were prepared starting from hydroxybenziodoxolones and alkynes in the presence of trifluoromethanesulfonic acid. The reaction of these compounds with azide anion leads to β-azido vinylbenziodoxolones as products of vinylic nucleophilic substitution in which addition-elimination reactions occur and the double bond configuration is retained. The structures of β-trifluorosulfonyloxy vinylbenziodoxolone and β-azido vinylbenziodoxolone were established by single crystal X-ray diffraction.
שפה:	אנגלית
יצא לאור:	2021
נושאים:	электронный ресурс труды учёных ТПУ hypervalent iodine vinylbenziodoxolones alkenyliodonium pseudocyclic Micheal acceptor гипервалентный йод
גישה מקוונת:	https://doi.org/10.1002/adsc.202100341
פורמט:	אלקטרוני Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667947

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