Preparation, Structure, and Reactivity of Pseudocyclic β-Trifluorosulfonyloxy Vinylbenziodoxolone Derivatives; Advanced Synthesis and Catalysis; Vol. 363, iss. 13

Preparation, Structure, and Reactivity of Pseudocyclic β-Trifluorosulfonyloxy Vinylbenziodoxolone Derivatives; Advanced Synthesis and Catalysis; Vol. 363, iss. 13

Bibliografiska uppgifter
Parent link:	Advanced Synthesis and Catalysis Vol. 363, iss. 13.— 2021.— [P. 3365-3371]
Institutionell upphovsman:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Övriga upphovsmän:	Yoshimura A. Akira, Huss Ch. D. Christopher, Mackenzie L. Liebl, Rohde G. L. Gregory, Larson S. M. Scott, Frahm G. B. Gunnar, Mattew W. L. W. Luedtke, Tanner J. Sh. J. Schumacher, Gardner S., Zhdankin V. V. Viktor Vladimirovich, Postnikov P. S. Pavel Sergeevich, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Tsugio K. Kitamura, Saito A. Akio
Sammanfattning:	Title screen Pseudocyclic β-trifluorosulfonyloxy vinylbenziodoxolones were prepared starting from hydroxybenziodoxolones and alkynes in the presence of trifluoromethanesulfonic acid. The reaction of these compounds with azide anion leads to β-azido vinylbenziodoxolones as products of vinylic nucleophilic substitution in which addition-elimination reactions occur and the double bond configuration is retained. The structures of β-trifluorosulfonyloxy vinylbenziodoxolone and β-azido vinylbenziodoxolone were established by single crystal X-ray diffraction.
Språk:	engelska
Publicerad:	2021
Ämnen:	электронный ресурс труды учёных ТПУ hypervalent iodine vinylbenziodoxolones alkenyliodonium pseudocyclic Micheal acceptor гипервалентный йод
Länkar:	https://doi.org/10.1002/adsc.202100341
Materialtyp:	Elektronisk Bokavsnitt
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667947

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