Preparation, Structure, and Reactivity of Pseudocyclic β-Trifluorosulfonyloxy Vinylbenziodoxolone Derivatives

Preparation, Structure, and Reactivity of Pseudocyclic β-Trifluorosulfonyloxy Vinylbenziodoxolone Derivatives

Dades bibliogràfiques
Parent link:	Advanced Synthesis and Catalysis Vol. 363, iss. 13.— 2021.— [P. 3365-3371]
Autor corporatiu:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Altres autors:	Yoshimura A. Akira, Huss Ch. D. Christopher, Mackenzie L. Liebl, Rohde G. L. Gregory, Larson S. M. Scott, Frahm G. B. Gunnar, Mattew W. L. W. Luedtke, Tanner J. Sh. J. Schumacher, Gardner S., Zhdankin V. V. Viktor Vladimirovich, Postnikov P. S. Pavel Sergeevich, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Tsugio K. Kitamura, Saito A. Akio
Sumari:	Title screen Pseudocyclic β-trifluorosulfonyloxy vinylbenziodoxolones were prepared starting from hydroxybenziodoxolones and alkynes in the presence of trifluoromethanesulfonic acid. The reaction of these compounds with azide anion leads to β-azido vinylbenziodoxolones as products of vinylic nucleophilic substitution in which addition-elimination reactions occur and the double bond configuration is retained. The structures of β-trifluorosulfonyloxy vinylbenziodoxolone and β-azido vinylbenziodoxolone were established by single crystal X-ray diffraction.
Publicat:	2021
Matèries:	электронный ресурс труды учёных ТПУ hypervalent iodine vinylbenziodoxolones alkenyliodonium pseudocyclic Micheal acceptor гипервалентный йод
Accés en línia:	https://doi.org/10.1002/adsc.202100341
Format:	Electrònic Capítol de llibre
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667947

Internet

https://doi.org/10.1002/adsc.202100341