Preparation, Structure, and Reactivity of Pseudocyclic β-Trifluorosulfonyloxy Vinylbenziodoxolone Derivatives

Preparation, Structure, and Reactivity of Pseudocyclic β-Trifluorosulfonyloxy Vinylbenziodoxolone Derivatives

Bibliografski detalji
Parent link:	Advanced Synthesis and Catalysis Vol. 363, iss. 13.— 2021.— [P. 3365-3371]
Autor kompanije:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Daljnji autori:	Yoshimura A. Akira, Huss Ch. D. Christopher, Mackenzie L. Liebl, Rohde G. L. Gregory, Larson S. M. Scott, Frahm G. B. Gunnar, Mattew W. L. W. Luedtke, Tanner J. Sh. J. Schumacher, Gardner S., Zhdankin V. V. Viktor Vladimirovich, Postnikov P. S. Pavel Sergeevich, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Tsugio K. Kitamura, Saito A. Akio
Sažetak:	Title screen Pseudocyclic β-trifluorosulfonyloxy vinylbenziodoxolones were prepared starting from hydroxybenziodoxolones and alkynes in the presence of trifluoromethanesulfonic acid. The reaction of these compounds with azide anion leads to β-azido vinylbenziodoxolones as products of vinylic nucleophilic substitution in which addition-elimination reactions occur and the double bond configuration is retained. The structures of β-trifluorosulfonyloxy vinylbenziodoxolone and β-azido vinylbenziodoxolone were established by single crystal X-ray diffraction.
Jezik:	engleski
Izdano:	2021
Teme:	электронный ресурс труды учёных ТПУ hypervalent iodine vinylbenziodoxolones alkenyliodonium pseudocyclic Micheal acceptor гипервалентный йод
Online pristup:	https://doi.org/10.1002/adsc.202100341
Format:	Elektronički Poglavlje knjige
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667947

Internet

https://doi.org/10.1002/adsc.202100341