Preparation, Structure, and Reactivity of Pseudocyclic β-Trifluorosulfonyloxy Vinylbenziodoxolone Derivatives; Advanced Synthesis and Catalysis; Vol. 363, iss. 13

Preparation, Structure, and Reactivity of Pseudocyclic β-Trifluorosulfonyloxy Vinylbenziodoxolone Derivatives; Advanced Synthesis and Catalysis; Vol. 363, iss. 13

Bibliographische Detailangaben
Parent link:	Advanced Synthesis and Catalysis Vol. 363, iss. 13.— 2021.— [P. 3365-3371]
Körperschaft:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Weitere Verfasser:	Yoshimura A. Akira, Huss Ch. D. Christopher, Mackenzie L. Liebl, Rohde G. L. Gregory, Larson S. M. Scott, Frahm G. B. Gunnar, Mattew W. L. W. Luedtke, Tanner J. Sh. J. Schumacher, Gardner S., Zhdankin V. V. Viktor Vladimirovich, Postnikov P. S. Pavel Sergeevich, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Tsugio K. Kitamura, Saito A. Akio
Zusammenfassung:	Title screen Pseudocyclic β-trifluorosulfonyloxy vinylbenziodoxolones were prepared starting from hydroxybenziodoxolones and alkynes in the presence of trifluoromethanesulfonic acid. The reaction of these compounds with azide anion leads to β-azido vinylbenziodoxolones as products of vinylic nucleophilic substitution in which addition-elimination reactions occur and the double bond configuration is retained. The structures of β-trifluorosulfonyloxy vinylbenziodoxolone and β-azido vinylbenziodoxolone were established by single crystal X-ray diffraction.
Sprache:	Englisch
Veröffentlicht:	2021
Schlagworte:	электронный ресурс труды учёных ТПУ hypervalent iodine vinylbenziodoxolones alkenyliodonium pseudocyclic Micheal acceptor гипервалентный йод
Online-Zugang:	https://doi.org/10.1002/adsc.202100341
Format:	Elektronisch Buchkapitel
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667947

Online

https://doi.org/10.1002/adsc.202100341