Preparation, Structure, and Reactivity of Pseudocyclic β-Trifluorosulfonyloxy Vinylbenziodoxolone Derivatives; Advanced Synthesis and Catalysis; Vol. 363, iss. 13
| Parent link: | Advanced Synthesis and Catalysis Vol. 363, iss. 13.— 2021.— [P. 3365-3371] |
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| Müşterek Yazar: | |
| Diğer Yazarlar: | , , , , , , , , , , , , , |
| Özet: | Title screen Pseudocyclic β-trifluorosulfonyloxy vinylbenziodoxolones were prepared starting from hydroxybenziodoxolones and alkynes in the presence of trifluoromethanesulfonic acid. The reaction of these compounds with azide anion leads to β-azido vinylbenziodoxolones as products of vinylic nucleophilic substitution in which addition-elimination reactions occur and the double bond configuration is retained. The structures of β-trifluorosulfonyloxy vinylbenziodoxolone and β-azido vinylbenziodoxolone were established by single crystal X-ray diffraction. |
| Dil: | İngilizce |
| Baskı/Yayın Bilgisi: |
2021
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| Konular: | |
| Online Erişim: | https://doi.org/10.1002/adsc.202100341 |
| Materyal Türü: | Elektronik Kitap Bölümü |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667947 |
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| 200 | 1 | |a Preparation, Structure, and Reactivity of Pseudocyclic β-Trifluorosulfonyloxy Vinylbenziodoxolone Derivatives |f A. Yoshimura, Ch. D. Huss, L. Mackenzie [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 16 tit.] | ||
| 330 | |a Pseudocyclic β-trifluorosulfonyloxy vinylbenziodoxolones were prepared starting from hydroxybenziodoxolones and alkynes in the presence of trifluoromethanesulfonic acid. The reaction of these compounds with azide anion leads to β-azido vinylbenziodoxolones as products of vinylic nucleophilic substitution in which addition-elimination reactions occur and the double bond configuration is retained. The structures of β-trifluorosulfonyloxy vinylbenziodoxolone and β-azido vinylbenziodoxolone were established by single crystal X-ray diffraction. | ||
| 461 | |t Advanced Synthesis and Catalysis | ||
| 463 | |t Vol. 363, iss. 13 |v [P. 3365-3371] |d 2021 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a hypervalent iodine | |
| 610 | 1 | |a vinylbenziodoxolones | |
| 610 | 1 | |a alkenyliodonium | |
| 610 | 1 | |a pseudocyclic | |
| 610 | 1 | |a Micheal acceptor | |
| 610 | 1 | |a гипервалентный йод | |
| 701 | 1 | |a Yoshimura |b A. |c chemical engineer |c Professor of Tomsk Polytechnic University |f 1981- |g Akira |3 (RuTPU)RU\TPU\pers\39852 | |
| 701 | 1 | |a Huss |b Ch. D. |g Christopher | |
| 701 | 1 | |a Mackenzie |b L. |g Liebl | |
| 701 | 1 | |a Rohde |b G. L. |g Gregory | |
| 701 | 1 | |a Larson |b S. M. |g Scott | |
| 701 | 1 | |a Frahm |b G. B. |g Gunnar | |
| 701 | 1 | |a Mattew |b W. L. |g W. Luedtke | |
| 701 | 1 | |a Tanner |b J. Sh. |g J. Schumacher | |
| 701 | 1 | |a Gardner |b S. | |
| 701 | 1 | |a Zhdankin |b V. V. |c химик |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1956- |g Viktor Vladimirovich |3 (RuTPU)RU\TPU\pers\35758 | |
| 701 | 1 | |a Postnikov |b P. S. |c organic chemist |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1984- |g Pavel Sergeevich |3 (RuTPU)RU\TPU\pers\31287 |9 15465 | |
| 701 | 1 | |a Yusubov |b M. S. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1961- |g Mekhman Suleiman-Ogly (Suleimanovich) |3 (RuTPU)RU\TPU\pers\31833 |9 15928 | |
| 701 | 1 | |a Tsugio |b K. |g Kitamura | |
| 701 | 1 | |a Saito |b A. |g Akio | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
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