Chemodivergent difunctionalization of alkenes through base-controlled radical relay

Bibliographic Details
Parent link:Chem
Vol. 8, iss. 1.— 2022.— [P. 12-14]
Main Author: Shatsky A. I. Andrey Ivanovich
Corporate Author: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Other Authors: Alvey G. R. Gregory, Karkas M. D. Markus
Summary:Title screen
Establishing chemodivergent synthetic strategies remains a daunting task in the realm of free-radical reaction manifolds. In the December issue of Chem, Glorius and co-workers resolve this challenge for selective difunctionalization of aliphatic alkenes. In the disclosed light-promoted radical relay process, switchable trifluoromethylation/alkylation or trifluoromethylation/sulfonylation of alkenes is achieved.
Режим доступа: по договору с организацией-держателем ресурса
Published: 2022
Subjects:
Online Access:https://doi.org/10.1016/j.chempr.2021.12.018
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667470