Comparative Evaluation of Spark Plasma and Conventional Sintering of NiO/YSZ Layers for Metal-Supported Solid Oxide Fuel Cells

Bibliographic Details
Parent link:High Temperature Materials and Processes
Vol. 37, iss. 4.— 2018.— [P. 351-356]
Corporate Authors: Национальный исследовательский Томский политехнический университет Инженерная школа энергетики Отделение электроэнергетики и электротехники, Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Научно-образовательный центр Б. П. Вейнберга
Other Authors: Ivashutenko A. S. Alexander Sergeevich, Ionov I. V. Igor Vyacheslavovich, Maznoy A. S. Anatoly Sergeevich, Sivkov A. A. Aleksandr Anatolyevich, Soloviev (Solovyev) A. A. Andrey Aleksandrovich
Summary:Title screen
NiO/YSZ anode layers for metal-supported solid oxide fuel cells (MS-SOFCs) were fabricated by spark plasma sintering (SPS). SPS parameters were optimized in order to achive anodes of the desired microstructure. The effect of sintering conditions on microstructure of NiO/ YSZ was studied by scanning electron microscopy and Xray diffractometry. Also NiO/YSZ layers were formed on porous metal supports by a screen-printing method and sintered in inert atmosphere and vacuum by conventional sintering technique. At temperatures above 1,200 °С in inert atmosphere and vacuum nickel oxide dissociation and its massive agglomeration are observed during conventional sintering. SPS process allows sintering of NiO/ YSZ granules without NiO dissociation, Ni agglomeration and the metal substrate oxidation at 1,100 °С. SPS sintered anodes demonstrate sufficiently homogeneous distribution of NiO and YSZ making a conduction path for electrons and ions. Well-bonded metal support/anode interface was obtained.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2018
Subjects:
Online Access:https://doi.org/10.1515/htmp-2016-0193
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=666763