Analysis of the High-Resolution Spectrum of Molecules in Doublet Electronic States: Fundamental ν3 Band of Chlorine Dioxide (16O35Cl16O) in the Ground Electronic State X 2B1; Optics and Spectroscopy; Vol. 129, iss. 8
| Parent link: | Optics and Spectroscopy Vol. 129, iss. 8.— 2021.— [P. 1090-1096] |
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| מחבר תאגידי: | |
| מחברים אחרים: | , , , |
| סיכום: | Title screen Using a Bruker IFS 125 HR Fourier spectrometer, the vibrational-rotational structure of the ClO2 molecule band ν3ν3 has been recorded with a resolution of 0.0015 cm-1. This band has been analyzed using an improved model of the effective Hamiltonian and a new computer program developed to analyze vibrational-rotational spectra of free radical molecules with an open shell, taking into account spin-rotational interactions. About 4200 transitions belonging to this band have been assigned with maximum values NmaxNmax = 68 and KmaxaKamax = 21. Subsequently, we have used these to determine a set of 13 spectroscopic parameters of the investigated vibrational state. The standard deviation results in the value drmsdrms = 2.4 × 10-4 cm-1. Режим доступа: по договору с организацией-держателем ресурса |
| שפה: | אנגלית |
| יצא לאור: |
2021
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| נושאים: | |
| גישה מקוונת: | https://doi.org/10.1134/S0030400X21080130 |
| פורמט: | אלקטרוני Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=666681 |
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| 200 | 1 | |a Analysis of the High-Resolution Spectrum of Molecules in Doublet Electronic States: Fundamental ν3 Band of Chlorine Dioxide (16O35Cl16O) in the Ground Electronic State X 2B1 |f M. A. Merkulova, A. N. Kakaulin, O. V. Gromova, E. S. Bekhtereva | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 31 tit.] | ||
| 330 | |a Using a Bruker IFS 125 HR Fourier spectrometer, the vibrational-rotational structure of the ClO2 molecule band ν3ν3 has been recorded with a resolution of 0.0015 cm-1. This band has been analyzed using an improved model of the effective Hamiltonian and a new computer program developed to analyze vibrational-rotational spectra of free radical molecules with an open shell, taking into account spin-rotational interactions. About 4200 transitions belonging to this band have been assigned with maximum values NmaxNmax = 68 and KmaxaKamax = 21. Subsequently, we have used these to determine a set of 13 spectroscopic parameters of the investigated vibrational state. The standard deviation results in the value drmsdrms = 2.4 × 10-4 cm-1. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Optics and Spectroscopy | ||
| 463 | |t Vol. 129, iss. 8 |v [P. 1090-1096] |d 2021 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a molecular spectroscopy | |
| 610 | 1 | |a chlorine dioxide | |
| 610 | 1 | |a vibrational-rotational Hamiltonian for doublet electronic state | |
| 610 | 1 | |a молекулярная спектроскопия | |
| 610 | 1 | |a диоксид хлора | |
| 701 | 1 | |a Merkulova |b M. A. |g Maria Andreevna |f 1996- |c physicist |c Engineer of Tomsk Polytechnic University |3 (RuTPU)RU\TPU\pers\46724 |9 22360 | |
| 701 | 1 | |a Kakaulin |b A. N. |c physicist |c Technician of Tomsk Polytechnic University |f 1998- |g Aleksey Nikolaevich |3 (RuTPU)RU\TPU\pers\47224 | |
| 701 | 1 | |a Gromova |b O. V. |c physicist |c Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences |f 1982- |g Olga Vasilievna |3 (RuTPU)RU\TPU\pers\34333 |9 17839 | |
| 701 | 1 | |a Bekhtereva |b E. S. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1974- |g Elena Sergeevna |3 (RuTPU)RU\TPU\pers\34450 |9 17851 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа физики высокоэнергетических процессов |c (2017- ) |3 (RuTPU)RU\TPU\col\23551 |
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