Analysis of the High-Resolution Spectrum of Molecules in Doublet Electronic States: Fundamental ν3 Band of Chlorine Dioxide (16O35Cl16O) in the Ground Electronic State X 2B1
| Parent link: | Optics and Spectroscopy Vol. 129, iss. 8.— 2021.— [P. 1090-1096] |
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| Співавтор: | |
| Інші автори: | , , , |
| Резюме: | Title screen Using a Bruker IFS 125 HR Fourier spectrometer, the vibrational-rotational structure of the ClO2 molecule band ν3ν3 has been recorded with a resolution of 0.0015 cm-1. This band has been analyzed using an improved model of the effective Hamiltonian and a new computer program developed to analyze vibrational-rotational spectra of free radical molecules with an open shell, taking into account spin-rotational interactions. About 4200 transitions belonging to this band have been assigned with maximum values NmaxNmax = 68 and KmaxaKamax = 21. Subsequently, we have used these to determine a set of 13 spectroscopic parameters of the investigated vibrational state. The standard deviation results in the value drmsdrms = 2.4 × 10-4 cm-1. Режим доступа: по договору с организацией-держателем ресурса |
| Опубліковано: |
2021
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| Предмети: | |
| Онлайн доступ: | https://doi.org/10.1134/S0030400X21080130 |
| Формат: | Електронний ресурс Частина з книги |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=666681 |