Preparation, Structure, and Properties of Track-Etched Membranes Based on Polylactic Acid

Bibliographic Details
Parent link:Membranes and Membrane Technologies
Vol. 3, iss. 5.— 2021.— [P. 282-290]
Corporate Authors: Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Научно-образовательный центр Б. П. Вейнберга, Национальный исследовательский Томский политехнический университет Исследовательская школа физики высокоэнергетических процессов
Other Authors: Ivanova N. M. Nina Mikhailovna, Filippova E. O. Ekaterina Olegovna, Tverdokhlebov S. I. Sergei Ivanovich, Levkovich N. V. Nataljya Vladimirovna, Apel P. Yu. Pavel Yurjevich
Summary:Title screen
New applications, in particular in medicine, require the creation of track-etched membranes (TMs) with fundamentally new properties. There are well-known TMs made from polycarbonate, polyimide, polypropylene, polyethylene terephthalate, polyethylene naphthalate, and polyvinylidene fluoride; that is, polymers characterized by high chemical resistance. This study focuses on the development of a membrane made of the biodegradable polymer polylactic acid (PLA). Films prepared from a 1% solution of polylactic acid with a molecular weight of Mw=121000 g/mol were taken as the initial matrix for TM fabrication. The films were irradiated with 1.2-MeV Xe ions at a fluence of 3.1•107 cm-2 on an IC-100 cyclotron. Etching was carried out in NaOH solutions of various concentrations (0.1, 1, or 2 mol/L) with varying the temperature from 18 to 70°С and the treatment time from 5 to 30 min. It has been revealed that the optimal treatment conditions for irradiated PLA films are etching in 1 M NaOH at a temperature of 44°C. This mode, with a time variation from 10 to 30 min, makes it possible to obtain through pores with a diameter of 0.6 to 1.5 µm with channel geometry close to cylindrical. It has been found that an increase in the etching time over 20 min leads to a decrease in the roughness of both membrane sides.
Режим доступа: по договору с организацией-держателем ресурса
Published: 2021
Subjects:
Online Access:https://doi.org/10.1134/S2517751621050073
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=666308