Oxidative cycloaddition of hydroxamic acids with dienes or guaiacols mediated by iodine(III) reagents

Oxidative cycloaddition of hydroxamic acids with dienes or guaiacols mediated by iodine(III) reagents

গ্রন্থ-পঞ্জীর বিবরন
Parent link:Beilstein Journal of Organic Chemistry.— , 2015-
Vol. 14.— 2018.— [P. 531-536]
সংস্থা লেখক: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
অন্যান্য লেখক: Shimizu H. Hisato, Yoshimura A. Akira, Noguchi K. Keiichi, Nemykin V. N. Victor, Zhdankin V. V. Viktor, Saito A. Akio
সংক্ষিপ্ত:Title screen
[Bis(trifluoroacetoxy)iodo]benzene (BTI) and (diacetoxyiodo)benzene (DIB) efficiently promote the formation of acylnitroso species from hydroxamic acids in the presence of various dienes to give the corresponding hetero-Diels-Alder (HDA) adducts in moderate to high yields. The present method could be applied to the HDA reactions of acylnitroso species with o-benzoquinones generated by the oxidative dearomatization of guaiacols.
প্রকাশিত: 2018
বিষয়গুলি:
электронный ресурс
труды учёных ТПУ
acylnitroso
benzoquinone
cycloaddition
dearomatization
iodine(III)
деароматизация
циклоприсоединение
йод
реагенты
অনলাইন ব্যবহার করুন:https://doi.org/10.3762/bjoc.14.39
বিন্যাস: বৈদ্যুতিক গ্রন্থের অধ্যায়
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664363
বিবরন
সংক্ষিপ্ত:Title screen
[Bis(trifluoroacetoxy)iodo]benzene (BTI) and (diacetoxyiodo)benzene (DIB) efficiently promote the formation of acylnitroso species from hydroxamic acids in the presence of various dienes to give the corresponding hetero-Diels-Alder (HDA) adducts in moderate to high yields. The present method could be applied to the HDA reactions of acylnitroso species with o-benzoquinones generated by the oxidative dearomatization of guaiacols.
ডিওআই:10.3762/bjoc.14.39

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