Oxidative cycloaddition of hydroxamic acids with dienes or guaiacols mediated by iodine(III) reagents

Bibliographic Details
Parent link:Beilstein Journal of Organic Chemistry.— , 2015-
Vol. 14.— 2018.— [P. 531-536]
Corporate Author: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Other Authors: Shimizu H. Hisato, Yoshimura A. Akira, Noguchi K. Keiichi, Nemykin V. N. Victor, Zhdankin V. V. Viktor, Saito A. Akio
Summary:Title screen
[Bis(trifluoroacetoxy)iodo]benzene (BTI) and (diacetoxyiodo)benzene (DIB) efficiently promote the formation of acylnitroso species from hydroxamic acids in the presence of various dienes to give the corresponding hetero-Diels-Alder (HDA) adducts in moderate to high yields. The present method could be applied to the HDA reactions of acylnitroso species with o-benzoquinones generated by the oxidative dearomatization of guaiacols.
Published: 2018
Subjects:
Online Access:https://doi.org/10.3762/bjoc.14.39
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664363