A study of products of tetrakis(hydroxymethyl)glycoluril dehydroxymethylation in aqueous solutions; Russian Chemical Bulletin; Vol. 70, iss. 1

A study of products of tetrakis(hydroxymethyl)glycoluril dehydroxymethylation in aqueous solutions; Russian Chemical Bulletin; Vol. 70, iss. 1

Bibliographische Detailangaben
Parent link:Russian Chemical Bulletin
Vol. 70, iss. 1.— 2021.— [P. 140-147]
Körperschaft: Национальный исследовательский Томский политехнический университет Инженерная школа новых производственных технологий Научно-образовательный центр Н. М. Кижнера
Weitere Verfasser: Panshina S. Svetlana, Ponomarenko O. V., Bakibaev A. A. Abdigali Abdimanapovich, Sidelnikov V. S. Vladimir Sergeevich, Kurgachev D. A. Dmitry Andreevich, Malkov V. S. Viktor Sergeevich, Khlebnikov A. I. Andrey Ivanovich, Tasheno A. K. Auezkhan Karipkhanovich
Zusammenfassung:Title screen
It was found that tetrakis(hydroxymethyl)glycoluril is unstable in aqueous solutions and undergoes stepwise dehydroxymethylation. The products of this process were identified by HPLC, 1D and 2D NMR spectroscopy. The main product of hydrolytic degradation at room temperature is tris(hydroxymethyl)glycoluril, which may be conditioned by the thermodynamic characteristics of the reaction. Further dehydroxymethylation to give di- and monohydroxymethyl glycoluril derivatives occurs under more severe conditions.
Режим доступа: по договору с организацией-держателем ресурса
Sprache:Englisch
Veröffentlicht: 2021
Schlagworte:
электронный ресурс
труды учёных ТПУ
tetrakis(hydroxymethyl)glycoluril
tris(hydroxymethyl)glycoluril
dehydroxymethylation
HPLC
NMR
COSY
HMBC
quantum chemical calculations
Online-Zugang:https://doi.org/10.1007/s11172-021-3068-8
Format: Elektronisch Buchkapitel
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664106

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