A study of products of tetrakis(hydroxymethyl)glycoluril dehydroxymethylation in aqueous solutions

A study of products of tetrakis(hydroxymethyl)glycoluril dehydroxymethylation in aqueous solutions

Λεπτομέρειες βιβλιογραφικής εγγραφής
Parent link:	Russian Chemical Bulletin Vol. 70, iss. 1.— 2021.— [P. 140-147]
Συγγραφή απο Οργανισμό/Αρχή:	Национальный исследовательский Томский политехнический университет Инженерная школа новых производственных технологий Научно-образовательный центр Н. М. Кижнера
Άλλοι συγγραφείς:	Panshina S. Svetlana, Ponomarenko O. V., Bakibaev A. A. Abdigali Abdimanapovich, Sidelnikov V. S. Vladimir Sergeevich, Kurgachev D. A. Dmitry Andreevich, Malkov V. S. Viktor Sergeevich, Khlebnikov A. I. Andrey Ivanovich, Tasheno A. K. Auezkhan Karipkhanovich
Περίληψη:	Title screen It was found that tetrakis(hydroxymethyl)glycoluril is unstable in aqueous solutions and undergoes stepwise dehydroxymethylation. The products of this process were identified by HPLC, 1D and 2D NMR spectroscopy. The main product of hydrolytic degradation at room temperature is tris(hydroxymethyl)glycoluril, which may be conditioned by the thermodynamic characteristics of the reaction. Further dehydroxymethylation to give di- and monohydroxymethyl glycoluril derivatives occurs under more severe conditions. Режим доступа: по договору с организацией-держателем ресурса
Γλώσσα:	Αγγλικά
Έκδοση:	2021
Θέματα:	электронный ресурс труды учёных ТПУ tetrakis(hydroxymethyl)glycoluril tris(hydroxymethyl)glycoluril dehydroxymethylation HPLC NMR COSY HMBC quantum chemical calculations
Διαθέσιμο Online:	https://doi.org/10.1007/s11172-021-3068-8
Μορφή:	Ηλεκτρονική πηγή Κεφάλαιο βιβλίου
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664106

Διαδίκτυο

https://doi.org/10.1007/s11172-021-3068-8