A study of products of tetrakis(hydroxymethyl)glycoluril dehydroxymethylation in aqueous solutions; Russian Chemical Bulletin; Vol. 70, iss. 1

Opis bibliograficzny
Parent link:Russian Chemical Bulletin
Vol. 70, iss. 1.— 2021.— [P. 140-147]
Korporacja: Национальный исследовательский Томский политехнический университет Инженерная школа новых производственных технологий Научно-образовательный центр Н. М. Кижнера
Kolejni autorzy: Panshina S. Svetlana, Ponomarenko O. V., Bakibaev A. A. Abdigali Abdimanapovich, Sidelnikov V. S. Vladimir Sergeevich, Kurgachev D. A. Dmitry Andreevich, Malkov V. S. Viktor Sergeevich, Khlebnikov A. I. Andrey Ivanovich, Tasheno A. K. Auezkhan Karipkhanovich
Streszczenie:Title screen
It was found that tetrakis(hydroxymethyl)glycoluril is unstable in aqueous solutions and undergoes stepwise dehydroxymethylation. The products of this process were identified by HPLC, 1D and 2D NMR spectroscopy. The main product of hydrolytic degradation at room temperature is tris(hydroxymethyl)glycoluril, which may be conditioned by the thermodynamic characteristics of the reaction. Further dehydroxymethylation to give di- and monohydroxymethyl glycoluril derivatives occurs under more severe conditions.
Режим доступа: по договору с организацией-держателем ресурса
Język:angielski
Wydane: 2021
Hasła przedmiotowe:
Dostęp online:https://doi.org/10.1007/s11172-021-3068-8
Format: Elektroniczne Rozdział
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664106