A study of products of tetrakis(hydroxymethyl)glycoluril dehydroxymethylation in aqueous solutions; Russian Chemical Bulletin; Vol. 70, iss. 1

A study of products of tetrakis(hydroxymethyl)glycoluril dehydroxymethylation in aqueous solutions; Russian Chemical Bulletin; Vol. 70, iss. 1

التفاصيل البيبلوغرافية
Parent link:Russian Chemical Bulletin
Vol. 70, iss. 1.— 2021.— [P. 140-147]
مؤلف مشترك: Национальный исследовательский Томский политехнический университет Инженерная школа новых производственных технологий Научно-образовательный центр Н. М. Кижнера
مؤلفون آخرون: Panshina S. Svetlana, Ponomarenko O. V., Bakibaev A. A. Abdigali Abdimanapovich, Sidelnikov V. S. Vladimir Sergeevich, Kurgachev D. A. Dmitry Andreevich, Malkov V. S. Viktor Sergeevich, Khlebnikov A. I. Andrey Ivanovich, Tasheno A. K. Auezkhan Karipkhanovich
الملخص:Title screen
It was found that tetrakis(hydroxymethyl)glycoluril is unstable in aqueous solutions and undergoes stepwise dehydroxymethylation. The products of this process were identified by HPLC, 1D and 2D NMR spectroscopy. The main product of hydrolytic degradation at room temperature is tris(hydroxymethyl)glycoluril, which may be conditioned by the thermodynamic characteristics of the reaction. Further dehydroxymethylation to give di- and monohydroxymethyl glycoluril derivatives occurs under more severe conditions.
Режим доступа: по договору с организацией-держателем ресурса
اللغة:الإنجليزية
منشور في: 2021
الموضوعات:
электронный ресурс
труды учёных ТПУ
tetrakis(hydroxymethyl)glycoluril
tris(hydroxymethyl)glycoluril
dehydroxymethylation
HPLC
NMR
COSY
HMBC
quantum chemical calculations
الوصول للمادة أونلاين:https://doi.org/10.1007/s11172-021-3068-8
التنسيق: الكتروني فصل الكتاب
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664106

الانترنت

https://doi.org/10.1007/s11172-021-3068-8

مواد مشابهة