A study of products of tetrakis(hydroxymethyl)glycoluril dehydroxymethylation in aqueous solutions; Russian Chemical Bulletin; Vol. 70, iss. 1
| Parent link: | Russian Chemical Bulletin Vol. 70, iss. 1.— 2021.— [P. 140-147] |
|---|---|
| מחבר תאגידי: | |
| מחברים אחרים: | , , , , , , , |
| סיכום: | Title screen It was found that tetrakis(hydroxymethyl)glycoluril is unstable in aqueous solutions and undergoes stepwise dehydroxymethylation. The products of this process were identified by HPLC, 1D and 2D NMR spectroscopy. The main product of hydrolytic degradation at room temperature is tris(hydroxymethyl)glycoluril, which may be conditioned by the thermodynamic characteristics of the reaction. Further dehydroxymethylation to give di- and monohydroxymethyl glycoluril derivatives occurs under more severe conditions. Режим доступа: по договору с организацией-держателем ресурса |
| שפה: | אנגלית |
| יצא לאור: |
2021
|
| נושאים: | |
| גישה מקוונת: | https://doi.org/10.1007/s11172-021-3068-8 |
| פורמט: | MixedMaterials אלקטרוני Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664106 |
MARC
| LEADER | 00000naa0a2200000 4500 | ||
|---|---|---|---|
| 001 | 664106 | ||
| 005 | 20250425134243.0 | ||
| 035 | |a (RuTPU)RU\TPU\network\35290 | ||
| 035 | |a RU\TPU\network\23279 | ||
| 090 | |a 664106 | ||
| 100 | |a 20210326d2021 k||y0rusy50 ba | ||
| 101 | 0 | |a eng | |
| 135 | |a drcn ---uucaa | ||
| 181 | 0 | |a i | |
| 182 | 0 | |a b | |
| 200 | 1 | |a A study of products of tetrakis(hydroxymethyl)glycoluril dehydroxymethylation in aqueous solutions |d Исследование продуктов дегидроксиметилирования тетракис(гидроксиметил)гликольурила в водных растворах |f S. Panshina, O. V. Ponomarenko, A. A. Bakibaev [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 18 tit.] | ||
| 330 | |a It was found that tetrakis(hydroxymethyl)glycoluril is unstable in aqueous solutions and undergoes stepwise dehydroxymethylation. The products of this process were identified by HPLC, 1D and 2D NMR spectroscopy. The main product of hydrolytic degradation at room temperature is tris(hydroxymethyl)glycoluril, which may be conditioned by the thermodynamic characteristics of the reaction. Further dehydroxymethylation to give di- and monohydroxymethyl glycoluril derivatives occurs under more severe conditions. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Russian Chemical Bulletin | ||
| 463 | |t Vol. 70, iss. 1 |v [P. 140-147] |d 2021 | ||
| 510 | 1 | |a Исследование продуктов дегидроксиметилирования тетракис(гидроксиметил)гликольурила в водных растворах |z rus | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a tetrakis(hydroxymethyl)glycoluril | |
| 610 | 1 | |a tris(hydroxymethyl)glycoluril | |
| 610 | 1 | |a dehydroxymethylation | |
| 610 | 1 | |a HPLC | |
| 610 | 1 | |a NMR | |
| 610 | 1 | |a COSY | |
| 610 | 1 | |a HMBC | |
| 610 | 1 | |a quantum chemical calculations | |
| 701 | 1 | |a Panshina |b S. |g Svetlana | |
| 701 | 1 | |a Ponomarenko |b O. V. | |
| 701 | 1 | |a Bakibaev |b A. A. |c Russian chemist |c Professor of TPU, doctor of chemical sciences |f 1960- |g Abdigali Abdimanapovich |3 (RuTPU)RU\TPU\pers\27851 | |
| 701 | 1 | |a Sidelnikov |b V. S. |g Vladimir Sergeevich | |
| 701 | 1 | |a Kurgachev |b D. A. |g Dmitry Andreevich | |
| 701 | 1 | |a Malkov |b V. S. |g Viktor Sergeevich | |
| 701 | 1 | |a Khlebnikov |b A. I. |c Chemist |c Professor of Tomsk Polytechnic University |f 1963- |g Andrey Ivanovich |3 (RuTPU)RU\TPU\pers\33927 |9 17500 | |
| 701 | 1 | |a Tasheno |b A. K. |g Auezkhan Karipkhanovich | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Инженерная школа новых производственных технологий |b Научно-образовательный центр Н. М. Кижнера |3 (RuTPU)RU\TPU\col\23556 |
| 801 | 0 | |a RU |b 63413507 |c 20210326 |g RCR | |
| 850 | |a 63413507 | ||
| 856 | 4 | |u https://doi.org/10.1007/s11172-021-3068-8 | |
| 942 | |c CF | ||