3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation; Microporous and Mesoporous Materials; Vol. 285

3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation; Microporous and Mesoporous Materials; Vol. 285

التفاصيل البيبلوغرافية
Parent link:Microporous and Mesoporous Materials
Vol. 285.— 2019.— [P. 80-88]
مؤلف مشترك: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
مؤلفون آخرون: Ciprian M. Matteo, Ruiz K. H. Karla Hernandez, Kassymova M. Meruyert, Wang Tingting, Zhuiykov S. Serge, Chaemchuen Somboon, Tu Rong, Verpoort F. V. K. Frensis Valter Kornelius
الملخص:Title screen
3D metal N-doped carbon frameworks (M-NCFs) are produced from the direct pyrolysis of 2D zeolitic imidazolate frameworks (ZIF-L Zn and Co) in a reducing atmosphere. The effects of the thermal treatment were studied in order to achieve the desired catalyst. The results show that metal nanoparticles and N-doping species present in the carbon matrix have a direct influence on the catalytic performance. Zn/NCF-1000 displayed quantitative conversion and selectivity towards the chemical fixation of carbon dioxide through the cycloaddition with epoxides. Furthermore, the magnetic property of the newly synthesized Co/NCF-600 was used to demonstrate its superior stability and recyclability, retaining the same catalytic activity for more than 10 cycles.
Режим доступа: по договору с организацией-держателем ресурса
اللغة:الإنجليزية
منشور في: 2019
الموضوعات:
труды учёных ТПУ
электронный ресурс
ZIF-L
pyrolysis
CO2 fixation
carbonates
heterogeneous catalyst
пиролиз
карбонаты
гетерогенные катализаторы
الوصول للمادة أونلاين:https://doi.org/10.1016/j.micromeso.2019.04.053
التنسيق: الكتروني فصل الكتاب
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=662578

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