3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation

3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation

Bibliographic Details
Parent link:	Microporous and Mesoporous Materials Vol. 285.— 2019.— [P. 80-88]
Corporate Author:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Other Authors:	Ciprian M. Matteo, Ruiz K. H. Karla Hernandez, Kassymova M. Meruyert, Wang Tingting, Zhuiykov S. Serge, Chaemchuen Somboon, Tu Rong, Verpoort F. V. K. Frensis Valter Kornelius
Summary:	Title screen 3D metal N-doped carbon frameworks (M-NCFs) are produced from the direct pyrolysis of 2D zeolitic imidazolate frameworks (ZIF-L Zn and Co) in a reducing atmosphere. The effects of the thermal treatment were studied in order to achieve the desired catalyst. The results show that metal nanoparticles and N-doping species present in the carbon matrix have a direct influence on the catalytic performance. Zn/NCF-1000 displayed quantitative conversion and selectivity towards the chemical fixation of carbon dioxide through the cycloaddition with epoxides. Furthermore, the magnetic property of the newly synthesized Co/NCF-600 was used to demonstrate its superior stability and recyclability, retaining the same catalytic activity for more than 10 cycles. Режим доступа: по договору с организацией-держателем ресурса
Published:	2019
Subjects:	труды учёных ТПУ электронный ресурс ZIF-L pyrolysis CO2 fixation carbonates heterogeneous catalyst пиролиз карбонаты гетерогенные катализаторы
Online Access:	https://doi.org/10.1016/j.micromeso.2019.04.053
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=662578

Internet

https://doi.org/10.1016/j.micromeso.2019.04.053