3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation; Microporous and Mesoporous Materials; Vol. 285
| Parent link: | Microporous and Mesoporous Materials Vol. 285.— 2019.— [P. 80-88] |
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| Institution som forfatter: | |
| Andre forfattere: | , , , , , , , |
| Summary: | Title screen 3D metal N-doped carbon frameworks (M-NCFs) are produced from the direct pyrolysis of 2D zeolitic imidazolate frameworks (ZIF-L Zn and Co) in a reducing atmosphere. The effects of the thermal treatment were studied in order to achieve the desired catalyst. The results show that metal nanoparticles and N-doping species present in the carbon matrix have a direct influence on the catalytic performance. Zn/NCF-1000 displayed quantitative conversion and selectivity towards the chemical fixation of carbon dioxide through the cycloaddition with epoxides. Furthermore, the magnetic property of the newly synthesized Co/NCF-600 was used to demonstrate its superior stability and recyclability, retaining the same catalytic activity for more than 10 cycles. Режим доступа: по договору с организацией-держателем ресурса |
| Sprog: | engelsk |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://doi.org/10.1016/j.micromeso.2019.04.053 |
| Format: | Electronisk Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=662578 |
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| 200 | 1 | |a 3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation |f M. Ciprian, K. H. Ruiz, M. Kassymova [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 79 tit.] | ||
| 330 | |a 3D metal N-doped carbon frameworks (M-NCFs) are produced from the direct pyrolysis of 2D zeolitic imidazolate frameworks (ZIF-L Zn and Co) in a reducing atmosphere. The effects of the thermal treatment were studied in order to achieve the desired catalyst. The results show that metal nanoparticles and N-doping species present in the carbon matrix have a direct influence on the catalytic performance. Zn/NCF-1000 displayed quantitative conversion and selectivity towards the chemical fixation of carbon dioxide through the cycloaddition with epoxides. Furthermore, the magnetic property of the newly synthesized Co/NCF-600 was used to demonstrate its superior stability and recyclability, retaining the same catalytic activity for more than 10 cycles. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Microporous and Mesoporous Materials | ||
| 463 | |t Vol. 285 |v [P. 80-88] |d 2019 | ||
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a ZIF-L | |
| 610 | 1 | |a pyrolysis | |
| 610 | 1 | |a CO2 fixation | |
| 610 | 1 | |a carbonates | |
| 610 | 1 | |a heterogeneous catalyst | |
| 610 | 1 | |a пиролиз | |
| 610 | 1 | |a карбонаты | |
| 610 | 1 | |a гетерогенные катализаторы | |
| 701 | 1 | |a Ciprian |b M. |g Matteo | |
| 701 | 1 | |a Ruiz |b K. H. |g Karla Hernandez | |
| 701 | 1 | |a Kassymova |b M. |g Meruyert | |
| 701 | 0 | |a Wang Tingting | |
| 701 | 1 | |a Zhuiykov |b S. |g Serge | |
| 701 | 0 | |a Chaemchuen Somboon |c chemist-technologist |c researcher at Tomsk Polytechnic University, Ph.D |f 1984- |3 (RuTPU)RU\TPU\pers\42620 |9 21555 | |
| 701 | 0 | |a Tu Rong | |
| 701 | 1 | |a Verpoort |b F. V. K. |c Chemical Engineer |c Professor of Tomsk Polytechnic University, doctor of chemical Sciences |f 1963- |g Frensis Valter Kornelius |3 (RuTPU)RU\TPU\pers\35059 |9 18334 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |9 28334 |
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