Effect of temperature and pressure on mixed oxide solid solutions; Inorganic Chemistry Communications; Vol. 117
| Parent link: | Inorganic Chemistry Communications Vol. 117.— 2020.— [107965, 4 p.] |
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| Corporate Author: | |
| Other Authors: | , , , , , , , |
| Summary: | Title screen A hydrothermal synthesis of ZrW2-xMoxO8 (0 ≤ x ≤ 2) from the corresponding precursors is reported in this paper. High-temperature and high-pressure data are presented for the sample with x = 1.6. An increase in temperature initiates the phase transition from tetragonal precursor to orthorhombic-ZrW2-xMoxO8 (x = 1.6) with the subsequent formation of cubic and trigonal phases. The thermolysis parameter of the disordered cubic ZrW2-xMoxO8 (x = 1.6) phase is 803 K, and the coefficient of thermal expansion is α = -4.6∙10-6 K−1. Data on ZrW2-xMoxO8 (x = 1.6) structure as a function of pressure are obtained for the first time. Pressure-induced changes from cubic to orthorhombic ZrW2-xMoxO8 (x = 1.6) phase at 1.38 GPa are observed. The sample amorphization is irreversible during decompression. Режим доступа: по договору с организацией-держателем ресурса |
| Language: | English |
| Published: |
2020
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| Subjects: | |
| Online Access: | https://doi.org/10.1016/j.inoche.2020.107965 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=662462 |
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| 200 | 1 | |a Effect of temperature and pressure on mixed oxide solid solutions |f M. Yu. Petrushina, E. S. Dedova, K. V. Yusenko [et al.] | |
| 203 | |a Текст |c электронный | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 27 tit.] | ||
| 330 | |a A hydrothermal synthesis of ZrW2-xMoxO8 (0 ≤ x ≤ 2) from the corresponding precursors is reported in this paper. High-temperature and high-pressure data are presented for the sample with x = 1.6. An increase in temperature initiates the phase transition from tetragonal precursor to orthorhombic-ZrW2-xMoxO8 (x = 1.6) with the subsequent formation of cubic and trigonal phases. The thermolysis parameter of the disordered cubic ZrW2-xMoxO8 (x = 1.6) phase is 803 K, and the coefficient of thermal expansion is α = -4.6∙10-6 K−1. Data on ZrW2-xMoxO8 (x = 1.6) structure as a function of pressure are obtained for the first time. Pressure-induced changes from cubic to orthorhombic ZrW2-xMoxO8 (x = 1.6) phase at 1.38 GPa are observed. The sample amorphization is irreversible during decompression. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Inorganic Chemistry Communications | ||
| 463 | |t Vol. 117 |v [107965, 4 p.] |d 2020 | ||
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| 701 | 1 | |a Petrushina |b M. Yu. |g Mariya Yurjevna | |
| 701 | 1 | |a Dedova |b E. S. |c specialist in the field of material science |c Assistant of the Department of Tomsk Polytechnic University |f 1987- |g Elena Sergeevna |3 (RuTPU)RU\TPU\pers\34676 |9 18026 | |
| 701 | 1 | |a Yusenko |b K. V. |g Kirill Valerjevich | |
| 701 | 1 | |a Portnyagin |b A. S. |g Arseny Sergeevich | |
| 701 | 1 | |a Papunov |b E. K. |g Evgeny Konstantinovich | |
| 701 | 1 | |a Filatov |b E. Yu. |g Evgeny Yurjevich | |
| 701 | 1 | |a Korenev |b S. V. |g Sergey Vasiljevich | |
| 701 | 1 | |a Gubanov |b A. I. |g Aleksandr Iridievich | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Инженерная школа новых производственных технологий |b Отделение материаловедения |3 (RuTPU)RU\TPU\col\23508 |
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