Effect of temperature and pressure on mixed oxide solid solutions

Effect of temperature and pressure on mixed oxide solid solutions

Bibliographic Details
Parent link:	Inorganic Chemistry Communications Vol. 117.— 2020.— [107965, 4 p.]
Corporate Author:	Национальный исследовательский Томский политехнический университет Инженерная школа новых производственных технологий Отделение материаловедения
Other Authors:	Petrushina M. Yu. Mariya Yurjevna, Dedova E. S. Elena Sergeevna, Yusenko K. V. Kirill Valerjevich, Portnyagin A. S. Arseny Sergeevich, Papunov E. K. Evgeny Konstantinovich, Filatov E. Yu. Evgeny Yurjevich, Korenev S. V. Sergey Vasiljevich, Gubanov A. I. Aleksandr Iridievich
Summary:	Title screen A hydrothermal synthesis of ZrW2-xMoxO8 (0 ≤ x ≤ 2) from the corresponding precursors is reported in this paper. High-temperature and high-pressure data are presented for the sample with x = 1.6. An increase in temperature initiates the phase transition from tetragonal precursor to orthorhombic-ZrW2-xMoxO8 (x = 1.6) with the subsequent formation of cubic and trigonal phases. The thermolysis parameter of the disordered cubic ZrW2-xMoxO8 (x = 1.6) phase is 803 K, and the coefficient of thermal expansion is α = -4.6∙10-6 K−1. Data on ZrW2-xMoxO8 (x = 1.6) structure as a function of pressure are obtained for the first time. Pressure-induced changes from cubic to orthorhombic ZrW2-xMoxO8 (x = 1.6) phase at 1.38 GPa are observed. The sample amorphization is irreversible during decompression. Режим доступа: по договору с организацией-держателем ресурса
Published:	2020
Subjects:	электронный ресурс труды учёных ТПУ оксиды твердые растворы
Online Access:	https://doi.org/10.1016/j.inoche.2020.107965
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=662462

Internet

https://doi.org/10.1016/j.inoche.2020.107965