Effect of temperature and pressure on mixed oxide solid solutions

Effect of temperature and pressure on mixed oxide solid solutions

Detalhes bibliográficos
Parent link:Inorganic Chemistry Communications
Vol. 117.— 2020.— [107965, 4 p.]
Autor Corporativo: Национальный исследовательский Томский политехнический университет Инженерная школа новых производственных технологий Отделение материаловедения
Outros Autores: Petrushina M. Yu. Mariya Yurjevna, Dedova E. S. Elena Sergeevna, Yusenko K. V. Kirill Valerjevich, Portnyagin A. S. Arseny Sergeevich, Papunov E. K. Evgeny Konstantinovich, Filatov E. Yu. Evgeny Yurjevich, Korenev S. V. Sergey Vasiljevich, Gubanov A. I. Aleksandr Iridievich
Resumo:Title screen
A hydrothermal synthesis of ZrW2-xMoxO8 (0 ≤ x ≤ 2) from the corresponding precursors is reported in this paper. High-temperature and high-pressure data are presented for the sample with x = 1.6. An increase in temperature initiates the phase transition from tetragonal precursor to orthorhombic-ZrW2-xMoxO8 (x = 1.6) with the subsequent formation of cubic and trigonal phases. The thermolysis parameter of the disordered cubic ZrW2-xMoxO8 (x = 1.6) phase is 803 K, and the coefficient of thermal expansion is α = -4.6∙10-6 K−1. Data on ZrW2-xMoxO8 (x = 1.6) structure as a function of pressure are obtained for the first time. Pressure-induced changes from cubic to orthorhombic ZrW2-xMoxO8 (x = 1.6) phase at 1.38 GPa are observed. The sample amorphization is irreversible during decompression.
Режим доступа: по договору с организацией-держателем ресурса
Idioma:inglês
Publicado em: 2020
Assuntos:
электронный ресурс
труды учёных ТПУ
оксиды
твердые растворы
Acesso em linha:https://doi.org/10.1016/j.inoche.2020.107965
Formato: Recurso Eletrônico Capítulo de Livro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=662462
Descrição
Resumo:Title screen
A hydrothermal synthesis of ZrW2-xMoxO8 (0 ≤ x ≤ 2) from the corresponding precursors is reported in this paper. High-temperature and high-pressure data are presented for the sample with x = 1.6. An increase in temperature initiates the phase transition from tetragonal precursor to orthorhombic-ZrW2-xMoxO8 (x = 1.6) with the subsequent formation of cubic and trigonal phases. The thermolysis parameter of the disordered cubic ZrW2-xMoxO8 (x = 1.6) phase is 803 K, and the coefficient of thermal expansion is α = -4.6∙10-6 K−1. Data on ZrW2-xMoxO8 (x = 1.6) structure as a function of pressure are obtained for the first time. Pressure-induced changes from cubic to orthorhombic ZrW2-xMoxO8 (x = 1.6) phase at 1.38 GPa are observed. The sample amorphization is irreversible during decompression.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1016/j.inoche.2020.107965

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