Laboratory X-ray Diffraction Complex for In Situ Investigations of Structural Phase Evolution of Materials under Gaseous Atmosphere

Bibliographic Details
Parent link:Metals
Vol. 10, iss. 4.— 2020.— [447, 15 p.]
Corporate Author: Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Отделение экспериментальной физики
Other Authors: Syrtanov M. S. Maksim Sergeevich, Garanin G. V. Georgy Viktorovich, Kashkarov E. B. Egor Borisovich, Pushilina N. S. Natalia Sergeevna, Kudiyarov V. N. Victor Nikolaevich, Murashkina T. L. Tatiana Leonidovna
Summary:Title screen
In this work, a laboratory X-ray diffraction complex for in situ investigations of structural phase evolution of materials under gaseous atmosphere and elevated temperatures was developed. The approbation of the complex was carried out using a commercially pure titanium (CP-Ti) powder, zirconium (Zr-1Nb) alloy and electron beam melted Ti-6Al-4V alloy. It was established that hydrogenation of the CP-Ti powder occurred at a temperature of 500 °C and a hydrogen pressure of 0.5 atm, accompanied by the formation of metastable ? titanium hydride (?-TiH) phase. The lifetime of the ?-TiH phase was 35–40 min. Decomposition of the ?-TiH occurred after reaching a temperature of 650 °C as a result of the thermally stimulated desorption of hydrogen. The a-Zr ? d-ZrH phase transformation was observed under hydrogenation of the zirconium Zr-1Nb alloy at a temperature of 350 °C and a hydrogen pressure of 0.5 atm. It was revealed that the increase in hydrogenation temperature to 450 °C accelerated this transformation by two times. Hydrogenation of the electron beam melted titanium Ti-6Al-4V alloy at a temperature of 650 °C and hydrogen pressure of 0.5 atm was accompanied by the a ? a + Я ? Я + a2 phase transformations.
Published: 2020
Subjects:
Online Access:http://earchive.tpu.ru/handle/11683/64876
https://doi.org/10.3390/met10040447
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=662171