Composite material WC1-x@C as a noble-metal-economic material for hydrogen evolution reaction

Bibliographic Details
Parent link:Journal of Alloys and Compounds
Vol. 834.— 2020.— [155116, 9 p.]
Corporate Author: Национальный исследовательский Томский политехнический университет Инженерная школа энергетики Отделение электроэнергетики и электротехники (ОЭЭ)
Other Authors: Shanenkov I. I. Ivan Igorevich, Ivashutenko A. S. Alexander Sergeevich, Shanenkova Yu. L. Yuliya Leonidovna, Nikitin D. S. Dmitry Sergeevich, Zhu Yukun, Khan Vey, Sivkov A. A. Aleksandr Anatolyevich
Summary:Title screen
Improving the hydrogen evolution reaction (HER) kinetics for sustainable hydrogen production requires decreasing the usage of noble metals and finding new stable co-catalysts. A new composite material based on cubic tungsten carbide embedded in the carbon matrix (WC1-x@C) was successfully prepared by a simple and scalable method of the plasma dynamic synthesis. The structure and morphology features were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), and RAMAN spectroscopy. The as-prepared composite WC1-x@C was found to be able to play a role of a co-catalyst in HER and sufficiently improve its kinetics when modified with a small amount of platinum. The WC1-x@C composite containing only 10 wt% of platinum has almost the same catalytic activity as a commercial Pt/C catalyst.
Режим доступа: по договору с организацией-держателем ресурса
Published: 2020
Subjects:
Online Access:https://doi.org/10.1016/j.jallcom.2020.155116
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=662132