Oxidative addition of verdazyl halogenides to Pd(PPh3)4; New Journal of Chemistry; Vol. 43, iss. 38
| Parent link: | New Journal of Chemistry Vol. 43, iss. 38.— 2019.— [P. 15293-15301] |
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| Coauteur: | |
| Andere auteurs: | , , , , , , , , |
| Samenvatting: | Title screen Direct oxidative addition of verdazyl halogenides to Pd(0) was studied and the role of this step in the Pd-catalyzed cross-coupling reactions was evaluated. A number of bis(triphenylphosphine)[verdazyl]palladium(II) iodide species were synthesized in yields of 89 to 92% and were shown to be persistent under ambient conditions. High synthetic potential of Pd-verdazyls was demonstrated by their efficiency and reactivity in the Sonogashira coupling reaction. These derivatives significantly expand the modern synthetic tools for development of spin-labeled materials and polyradical systems with desired functionalities. Режим доступа: по договору с организацией-держателем ресурса |
| Taal: | Engels |
| Gepubliceerd in: |
2019
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| Onderwerpen: | |
| Online toegang: | https://doi.org/10.1039/C9NJ03361K |
| Formaat: | MixedMaterials Elektronisch Hoofdstuk |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=661964 |
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| 200 | 1 | |a Oxidative addition of verdazyl halogenides to Pd(PPh3)4 |f P. V. Petunin, D. E. Votkina, M. E. Trusova [et al.] | |
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| 300 | |a Title screen | ||
| 330 | |a Direct oxidative addition of verdazyl halogenides to Pd(0) was studied and the role of this step in the Pd-catalyzed cross-coupling reactions was evaluated. A number of bis(triphenylphosphine)[verdazyl]palladium(II) iodide species were synthesized in yields of 89 to 92% and were shown to be persistent under ambient conditions. High synthetic potential of Pd-verdazyls was demonstrated by their efficiency and reactivity in the Sonogashira coupling reaction. These derivatives significantly expand the modern synthetic tools for development of spin-labeled materials and polyradical systems with desired functionalities. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t New Journal of Chemistry | ||
| 463 | |t Vol. 43, iss. 38 |v [P. 15293-15301] |d 2019 | ||
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