Oxidative addition of verdazyl halogenides to Pd(PPh3)4

Oxidative addition of verdazyl halogenides to Pd(PPh3)4

Bibliographic Details
Parent link:	New Journal of Chemistry Vol. 43, iss. 38.— 2019.— [P. 15293-15301]
Corporate Author:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Other Authors:	Petunin P. V. Pavel Vasilievich, Votkina D. E. Darjya Evgenjevna, Trusova M. E. Marina Evgenievna, Rybalova T. V. Tatjyana Valerjevna, Amosov E. V. Evgeny Valerjevich, Uvarov M. N. Mikhail Nikolaevich, Postnikov P. S. Pavel Sergeevich, Kazantsev M. S. Maksim Sergeevich, Mostovich E. A. Evgeny Alekseevich
Summary:	Title screen Direct oxidative addition of verdazyl halogenides to Pd(0) was studied and the role of this step in the Pd-catalyzed cross-coupling reactions was evaluated. A number of bis(triphenylphosphine)[verdazyl]palladium(II) iodide species were synthesized in yields of 89 to 92% and were shown to be persistent under ambient conditions. High synthetic potential of Pd-verdazyls was demonstrated by their efficiency and reactivity in the Sonogashira coupling reaction. These derivatives significantly expand the modern synthetic tools for development of spin-labeled materials and polyradical systems with desired functionalities. Режим доступа: по договору с организацией-держателем ресурса
Language:	English
Published:	2019
Subjects:	электронный ресурс труды учёных ТПУ окислительное присоединение
Online Access:	https://doi.org/10.1039/C9NJ03361K
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=661964

Internet

https://doi.org/10.1039/C9NJ03361K