Hetero Diels–Alder Reaction and Ene Reaction of Acylnitroso Species in situ Generated by Hypoiodite Catalysis; European Journal of Organic Chemistry; Vol. 2018, iss. 45

Hetero Diels–Alder Reaction and Ene Reaction of Acylnitroso Species in situ Generated by Hypoiodite Catalysis; European Journal of Organic Chemistry; Vol. 2018, iss. 45

Détails bibliographiques
Parent link:	European Journal of Organic Chemistry Vol. 2018, iss. 45.— 2018.— [P. 6199-6203]
Collectivité auteur:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Autres auteurs:	Uraoka S. Saki, Shinohara I. Ikumi, Shimizu H. Hisato, Noguchi K. Keiichi, Yoshimura A. Akira, Zhdankin V. V. Viktor Vladimirovich, Saito A. Akio
Résumé:	Title screen As a first non?metal?catalyzed oxidation for the in situ generation of acylnitroso species, we describe the hypoiodite catalysis using tetra?n?butylammonium iodide as precatalyst with tert?butyl hydroperoxide or hydrogen peroxide as a terminal oxidant. This method can be applied to hetero Diels–Alder (HDA) reactions with dienes and ene reactions with alkenes. Furthermore, the conversions of the representative HDA adduct to nitrone and 2?amino alcohols were demonstrated. Compared with previous metal?catalyzed oxidation methods, this work provides a more efficient and environmentally friendly procedure. Режим доступа: по договору с организацией-держателем ресурса
Langue:	anglais
Publié:	2018
Sujets:	электронный ресурс труды учёных ТПУ acylnitroso catalysis cycloaddition ene reaction iodine катализ циклоприсоединение
Accès en ligne:	https://doi.org/10.1002/ejoc.201801340
Format:	Électronique Chapitre de livre
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660275

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