Hetero Diels–Alder Reaction and Ene Reaction of Acylnitroso Species in situ Generated by Hypoiodite Catalysis; European Journal of Organic Chemistry; Vol. 2018, iss. 45

Hetero Diels–Alder Reaction and Ene Reaction of Acylnitroso Species in situ Generated by Hypoiodite Catalysis; European Journal of Organic Chemistry; Vol. 2018, iss. 45

書誌詳細
Parent link:	European Journal of Organic Chemistry Vol. 2018, iss. 45.— 2018.— [P. 6199-6203]
団体著者:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
その他の著者:	Uraoka S. Saki, Shinohara I. Ikumi, Shimizu H. Hisato, Noguchi K. Keiichi, Yoshimura A. Akira, Zhdankin V. V. Viktor Vladimirovich, Saito A. Akio
要約:	Title screen As a first non?metal?catalyzed oxidation for the in situ generation of acylnitroso species, we describe the hypoiodite catalysis using tetra?n?butylammonium iodide as precatalyst with tert?butyl hydroperoxide or hydrogen peroxide as a terminal oxidant. This method can be applied to hetero Diels–Alder (HDA) reactions with dienes and ene reactions with alkenes. Furthermore, the conversions of the representative HDA adduct to nitrone and 2?amino alcohols were demonstrated. Compared with previous metal?catalyzed oxidation methods, this work provides a more efficient and environmentally friendly procedure. Режим доступа: по договору с организацией-держателем ресурса
言語:	英語
出版事項:	2018
主題:	электронный ресурс труды учёных ТПУ acylnitroso catalysis cycloaddition ene reaction iodine катализ циклоприсоединение
オンライン･アクセス:	https://doi.org/10.1002/ejoc.201801340
フォーマット:	MixedMaterials 電子媒体図書の章
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660275

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