Hetero Diels–Alder Reaction and Ene Reaction of Acylnitroso Species in situ Generated by Hypoiodite Catalysis

Hetero Diels–Alder Reaction and Ene Reaction of Acylnitroso Species in situ Generated by Hypoiodite Catalysis

Bibliographic Details
Parent link:	European Journal of Organic Chemistry Vol. 2018, iss. 45.— 2018.— [P. 6199-6203]
Corporate Author:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Other Authors:	Uraoka S. Saki, Shinohara I. Ikumi, Shimizu H. Hisato, Noguchi K. Keiichi, Yoshimura A. Akira, Zhdankin V. V. Viktor Vladimirovich, Saito A. Akio
Summary:	Title screen As a first non?metal?catalyzed oxidation for the in situ generation of acylnitroso species, we describe the hypoiodite catalysis using tetra?n?butylammonium iodide as precatalyst with tert?butyl hydroperoxide or hydrogen peroxide as a terminal oxidant. This method can be applied to hetero Diels–Alder (HDA) reactions with dienes and ene reactions with alkenes. Furthermore, the conversions of the representative HDA adduct to nitrone and 2?amino alcohols were demonstrated. Compared with previous metal?catalyzed oxidation methods, this work provides a more efficient and environmentally friendly procedure. Режим доступа: по договору с организацией-держателем ресурса
Published:	2018
Subjects:	электронный ресурс труды учёных ТПУ acylnitroso catalysis cycloaddition ene reaction iodine катализ циклоприсоединение
Online Access:	https://doi.org/10.1002/ejoc.201801340
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660275

Internet

https://doi.org/10.1002/ejoc.201801340